Art

J-GLOBAL ID：201702285793790548   Reference number：17A0593052

Control of Vicinal Stereocenters through Nickel-Catalyzed Alkyl-Alkyl Cross-Coupling

ニッケル触媒アルキル-アルキル交差カップリングによる隣接立体中心の制御

Author (4)： Mu Xin (Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA, 91125, USA) ,  Shibata Yu (Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA, 91125, USA) ,  Makida Yusuke (Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA, 91125, USA) ,  Fu Gregory C. (Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA, 91125, USA)
Material： Angewandte Chemie. International Edition  (Angewandte Chemie. International Edition in English)
Volume： 56  Issue： 21  Page： 5821-5824  Publication year： 2017 
JST Material Number： H0127B  ISSN： 1433-7851  CODEN： ACIEAY  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *Alkylation ,  *nickel catalyst ,  *cross coupling reaction ,  asymmetric catalyst ,  nucleophilic reagent ,  *organozinc compound ,  *aliphatic iodine compound ,  *stereoselective reaction ,  alkyl halide ,  stereocenter ,  Pyrrolidines
Semi thesaurus term： Pyrrolidines

Author keywords (5)： alkylation ,  asymmetric synthesis ,  cross-coupling ,  nickel ,  zinc

JST classification (5)： Stereochemistry of organic reaction  (CF02130V) ,  Aliphatic halogen compounds  (CF03050P) ,  Pyrroles  (CF07076L) ,  Group 11 and group 12 organic compounds  (CF09052N) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (5)： Methyl iodide ,  Bis[1-(tert-butoxycarbonyl)-2-pyrrolidinyl] zinc ,  1-(tert-Butoxycarbonyl)-2-methylpyrrolidine ,  [(1S,3R)-3-Methylcyclohexyl] iodide ,  (2S)-2-[(1S,3R)-3-Methylcyclohexyl]pyrrolidine-1-carboxylic acid tert-butyl ester

Terms in the title (3)： ニッケル触媒 ,  交差カップリング ,  立体中心