Art

J-GLOBAL ID：201702285899266905   Reference number：17A0680385

DIASTEREO- AND ENANTIOSELECTIVE CONSTRUCTION OF 6,7-DIOXABICYCLO[2.2.1]HEPTANE DERIVATIVES BY A DIRHODIUM(II)-CATALYZED INTRAMOLECULAR C-H INSERTION REACTION

ジロジウム(II)触媒分子内C-H挿入反応による6,7-ジオキサビシクロ[2.2.1]ヘプタン誘導体のジアステレオ選択的およびエナンチオ選択的構築

Author (7)： MIYAZAWA Taku (Hokkaido Univ., Sapporo, JPN) ,  IMAI Kozue (Hokkaido Univ., Sapporo, JPN) ,  ITO Motoki (Hokkaido Univ., Sapporo, JPN) ,  TAKEDA Koji (Hokkaido Univ., Sapporo, JPN) ,  ANADA Masahiro (Hokkaido Univ., Sapporo, JPN) ,  MATSUNAGA Shigeki (Hokkaido Univ., Sapporo, JPN) ,  HASHIMOTO Shunichi (Hokkaido Univ., Sapporo, JPN)
Material： Heterocycles  (International Journal for Reviews and Communications in Heterocyclic Chemistry)
Volume： 95  Issue： 2  Page： 1211-1229  Publication year： Jan. 25, 2017 
JST Material Number： S0966A  ISSN： 0385-5414  CODEN： HTCYAM  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： rhodium complex ,  rhodium catalyst ,  catalytic reaction ,  C-H bond ,  *insertion reaction ,  bridged compound ,  asymmetric synthesis ,  oxygen heterocyclic compound ,  cyclic ether
Semi thesaurus term： *Dioxolanes ,  tetrahydrofurans ,  bridged compound

JST classification (2)： Catalytic reactions in general  (CB06080F) ,  Dioxoles,oxathioles,dithioles  (CF07079K)

Substance index (6)： 2-Diazo-3-(2-phenethyl-1,3-dioxolane-2-yl)propanoic acid methyl ester ,  (1R,4S)-4-Phenethyl-5,7-dioxabicyclo[2.2.1]heptane-2β-carboxylic acid methyl ester ,  rel-(1R^*,4S^*)-4-Methyl-5,7-dioxabicyclo[2.2.1]heptane-2β^*-carboxylic acid methyl ester ,  rel-(1R^*,4S^*)-4-Ethyl-5,7-dioxabicyclo[2.2.1]heptane-2β^*-carboxylic acid methyl ester ,  rel-(1R^*,4S^*)-4-Methyl-5,7-dioxabicyclo[2.2.1]heptane-2β^*-methanol ,  rel-(1R^*,4S^*)-4-Ethyl-5,7-dioxabicyclo[2.2.1]heptane-2β^*-methanol

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Terms in the title (5)： 触媒 ,  挿入反応 ,  ヘプタン誘導体 ,  ジアステレオ選択 ,  構築