Art

J-GLOBAL ID：201702291210609375   Reference number：17A0519441

Total synthesis of myriocin and mycestericin D employing Rh(II)-catalyzed CH amination followed by stereoselective alkylation

Rh(II)触媒C-Hアミノ化とその後の立体選択的アルキル化を用いたミリオシンおよびミセステリシンDの全合成

Author (6)： Noda Narumi (Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama, Sugitani, Toyama 930-0194, Japan) ,  Nambu Hisanori (Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama, Sugitani, Toyama 930-0194, Japan) ,  Ubukata Kana (Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama, Sugitani, Toyama 930-0194, Japan) ,  Fujiwara Tomoya (Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama, Sugitani, Toyama 930-0194, Japan) ,  Tsuge Kiyoshi (Department of Chemistry, Graduate School of Science and Engineering, University of Toyama, Gofuku, Toyama 930-8555, Japan) ,  Yakura Takayuki (Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama, Sugitani, Toyama 930-0194, Japan)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 73  Issue： 7  Page： 868-878  Publication year： Feb. 16, 2017 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： total synthesis ,  asymmetric synthesis ,  rhodium catalyst ,  catalytic reaction ,  *Amination ,  *Alkylation ,  amidosulfuric acid ,  ester ,  oxygen heterocyclic compound ,  sulfur heterocyclic compound ,  nitrogen heterocyclic compound

Author keywords (5)： Total synthesis ,  CH amination ,  Alkylation ,  Cross metathesis ,  Rhodium

JST classification (2)： Catalytic reactions in general  (CB06080F) ,  Amino acids  (CF10070V)

Substance index (4)： Mycestericin D ,  Myriocin ,  (4S,5S)-2,2-Dimethyl-4-(tert-butyldiphenylsiloxymethyl)-5-(sulfamoyloxymethyl)-1,3-dioxolane ,  [2,2-Dimethyl-5-[(tert-butyldiphenylsilyloxy)methyl]-6α-formyl-1,3-dioxane-5α-yl]carbamic acid tert-butyl ester

Terms in the title (8)： Rh ,  触媒 ,  アミノ化 ,  立体 ,  アルキル化 ,  ミリオシン ,  ミセステリシンD ,  全合成