Art

J-GLOBAL ID：201702293672327287   Reference number：17A0509691

A dramatic synergistic effect of a flexible achiral linker on a rigid chiral cis-1,2-diamine bifunctional organocatalyst

剛性キラルcis-1,2-ジアミン二官能性有機触媒に及ぼす柔軟性アキラルリンカーの劇的な相乗効果

Author (6)： Matsunaga Hirofumi (Faculty of Life Sciences, Kumamoto University, 5-1 Oe-honmachi, Chuo-ku, Kumamoto 862-0973, Japan. [e-mail] [e-mail]) ,  Tajima Daisuke ,  Kawauchi Tetsuro ,  Yasuyama Takuro ,  Ando Shin ,  Ishizuka Tadao
Material： Organic & Biomolecular Chemistry  (Org Biomol Chem)
Volume： 15  Issue： 14  Page： 2892-2896  Publication year： 2017 
JST Material Number： A0499C  ISSN： 1477-0520  CODEN： OBCRAK  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *diamine ,  *catalyst ,  *organic compound ,  *urea compound ,  *organosulphur compound ,  Michael reaction ,  stereoselectivity ,  catalytic activity ,  asymmetric reaction ,  molecular structure ,  diketone ,  alkene ,  nitro compound ,  catalytic reaction ,  bridged compound ,  *amidation ,  enantioselectivity ,  linker ,  *organic catalyst ,  *thiourea derivatives ,  Bridged Bicyclo Compounds ,  aliphatic ketone
Semi thesaurus term： *thiourea derivatives ,  bicyclic compound

JST classification (3)： Aliphatic amines,imines,quaternary ammonium,immonium compounds  (CF03070L) ,  Other catalysts  (CB06123Z) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (17)： 3-((R)-1-(2-Thienyl)-2-nitroethyl)pentane-2,4-dione ,  3-((R)-1-(2-Furyl)-2-nitroethyl)pentane-2,4-dione ,  3-((R)-1-Nitro-4-phenylbutane-2-yl)pentane-2,4-dione ,  3-((R)-1-Nitropentane-2-yl)pentane-2,4-dione ,  3-[(S)-2-Chloro-α-(nitromethyl)benzyl]-2,4-pentanedione ,  3-[(S)-3-Chloro-α-(nitromethyl)benzyl]-2,4-pentanedione ,  3-[(S)-4-Chloro-α-(nitromethyl)benzyl]-2,4-pentanedione ,  3-[(S)-α-(Nitromethyl)-4-fluorobenzyl]-2,4-pentanedione ,  3-[(S)-α-(Nitromethyl)-4-methoxybenzyl]-2,4-pentanedione ,  3-((S)-1-(p-Tolyl)-2-nitroethyl)pentane-2,4-dione ,  3-((S)-1-(o-Tolyl)-2-nitroethyl)pentane-2,4-dione ,  (4S)-3-Acetyl-4-phenyl-5-nitro-2-pentanone ,  N-(16-Dimethylaminotetracyclo[6.6.2.0^2,7.0^9,14]hexadecane-2(7),3,5,9(14),10,12-hexaene-15-yl)-2-(3-(3,5-di(trifluoromethyl)phenyl)thioureido)acetamide ,  N-(16-Dimethylaminotetracyclo[6.6.2.0^2,7.0^9,14]hexadecane-2(7),3,5,9(14),10,12-hexaene-15-yl)-2-(3-(3,5-di(trifluoromethyl)phenyl)thioureido)butanamide ,  N-(16-Dimethylaminotetracyclo[6.6.2.0^2,7.0^9,14]hexadecane-2(7),3,5,9(14),10,12-hexaene-15-yl)-2-(3-(3,5-di(trifluoromethyl)phenyl)thioureido)propanamide ,  β-Nitrostyrene ,  Acetylacetone

Terms in the title (7)： 剛性 ,  キラル ,  CIS ,  ジアミン ,  官能性 ,  有機触媒 ,  相乗効果