Art

J-GLOBAL ID：201802229404433656   Reference number：18A0772082

Multivariate analysis of ¹³C NMR spectra to extract information about monomer sequences in poly(methyl methacrylate-co-benzyl methacrylate)s prepared by various polymer reactions

種々の高分子反応により調製したポリ(メタクリル酸メチル-co-メタクリル酸ベンジル)における単量体配列に関する情報を抽出するための¹³C NMRスペクトルの多変量解析

Author (4)： HSU Yuchin (Tokushima Univ., Tokushima, JPN) ,  CHUANG Mingyeh (Tokushima Univ., Tokushima, JPN) ,  HIRANO Tomohiro (Tokushima Univ., Tokushima, JPN) ,  UTE Koichi (Tokushima Univ., Tokushima, JPN)
Material： Polymer Journal
Volume： 50  Issue： 5  Page： 355-363  Publication year： May. 2018 
JST Material Number： F0612A  ISSN： 0032-3896  CODEN： POLJB8  Document type： Article
Article type： 原著論文  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *copolymer ,  *13C NMR ,  *principal component analysis ,  polymer chain ,  steric configuration ,  chemical composition ,  chain composition ,  hydrogenolysis ,  elimination reaction ,  hydrolysis ,  ester interchange ,  chemical modification ,  esterification ,  methylation ,  benzylation ,  polymethacrylate ,  polymethacrylic acid ,  radical polymerization ,  copolymerization ,  polymer reaction ,  aliphatic compound ,  diazo compound ,  aliphatic carboxylic acid ,  olefin compound ,  unsaturated carboxylic acid ,  carboxylate(ester) ,  organobromine compound ,  benzyl halide
Semi thesaurus term： polybenzyl methacrylate ,  saponification ,  debenzylation

JST classification (1)： Spectra of polymers  (CG02033O)

Substance index (4)： Diazomethane ,  Methacrylic acid methyl ,  Methacrylic acid benzyl ,  Benzyl bromide

Reference (47)：

• Bovey FA, Polymer NMR, Spectroscopy. VI. Methyl methacrylate-styrene and methyl methacrylate-alpha-methylstyrene copolymers. J Polym Sci. 1962;62:197-209.
• Hirai H, Koinuma H, Tanabe T, Takeuchi K. Polymerization of coordinated monomers. XV. 13C-NMR study on the alternating copolymers of methyl methacrylate with styrene. J Polym Sci Polym Chem. 1979;17:1339-52.
• San Roman J, Madruga EL, Del Puerto MA. Microstructure and tacticity in radical copolymerization. I. Proton NMR of styrene-methyl methacrylate copolymers. Angew Makromol Chem. 1979;78:129-43.
• Aerdts AM, de Haan JW, German AL. Proton and carbon NMR spectra of alternating and statistical styrene-methyl methacrylate copolymers revisited. Macromolecules. 1993;26:1965-71.
• Chujo R, Satoh S, Nagai E. High resolution NMR study of vinylidene chloride-vinyl chloride copolymer. J Polym Sci, Part A. 1964;2:895-905.

Terms in the title (8)： 高分子反応 ,  調製 ,  メタクリル酸メチル ,  CO ,  メタクリル酸ベンジル ,  単量体 ,  NMRスペクトル ,  多変量解析