Art

J-GLOBAL ID：201802238601136102   Reference number：18A0551418

A Formal anti-Markovnikov Hydroalkoxylation of Allylic Alcohols with a Ruthenium Catalyst

ルテニウム触媒によるアリルアルコールの形式的反Markovnikovヒドロアルコキシ化

Author (3)： Nakamura Yushi (Department of Biomedical Information, Faculty of Life and Medical Sciences, Doshisha University) ,  Ohta Tetsuo (Department of Biomedical Information, Faculty of Life and Medical Sciences, Doshisha University) ,  Oe Yohei (Department of Biomedical Information, Faculty of Life and Medical Sciences, Doshisha University)
Material： Chemistry Letters  (Chem Lett)
Volume： 47  Issue： 3  Page： 288-291(J-STAGE)  Publication year： 2018 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *ruthenium catalyst ,  *Markovnikov rule ,  *addition reaction ,  C-C bond ,  double bond ,  *allyl compound ,  *aliphatic alcohol ,  *unsaturated alcohol ,  nucleophilic reaction ,  ruthenium complex ,  condition ,  reaction mechanism
Semi thesaurus term： *hydroalkoxylation ,  condition of reaction

Author keywords (3)： Hydroalkoxylation ,  Allylic alcohols ,  Ruthenium catalyst

JST classification (2)： Catalytic reactions(homogeneous system)  (CB06090Q) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (5)： Allyl alcohol ,  3-Buten-2-ol ,  Ethanol ,  4-Ethoxy-2-butanol ,  N,N′-Dibutyl-4-piperidinopyridine-2,6-bismethaneimine

Reference (53)：

• 1) For recent examples of Williamson etherification for the construction of 3-alkoxypropan-1-ols in total syntheses, see: a) E. Brun, V. Bellosta, J. Cossy, J. Org. Chem. 2016, 81, 8206.
• 1) b) J. N. Kumar, B. Das, RSC Adv. 2015, 5, 14465.
• 1) c) C. N. Reddy, Q. Ye, S. Chourey, S. Gravel, W. S. Powell, J. Rokach, Tetrahedron Lett. 2015, 56, 6896.
• 1) d) A. Wadood, H. Kim, C. M. Park, J.-H. Song, S. Lee, Arch. Pharmacal Res. 2015, 38, 2029.
• 1) e) E. Brun, V. Bellosta, J. Cossy, J. Org. Chem. 2015, 80, 8668.

Terms in the title (3)： ルテニウム触媒 ,  アリルアルコール ,  ヒドロアルコキシ化