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J-GLOBAL ID：201802246550389759   Reference number：18A0664644

有機分子触媒 有機超強塩基触媒が拓く新たな炭素-炭素結合生成反応

Author (2)： KONDO AZUSA (東北大 大学院理学研究科) ,  TERADA MASAHIRO (東北大 大学院理学研究科)
Material： Chemical Times  (Chem Times)
Volume： 2018  Issue： 2  Page： 8-13  Publication year： Apr. 2018 
JST Material Number： G0724A  ISSN： 0285-2446  Document type： Article
Article type： 文献レビュー  Country of issue： Japan (JPN)  Language： JAPANESE (JA)

Thesaurus term： *catalyst ,  *base (alkali) ,  base catalytic reaction ,  *C-C bond ,  asymmetric synthesis ,  asymmetric catalyst ,  catalytic reaction ,  asymmetric reaction ,  stereoselectivity ,  addition reaction ,  *rearrangement reaction ,  phosphorylation ,  charge exchange ,  nucleophilic reagent ,  sulfur heterocyclic compound ,  enolate ,  carboxylate (ester) ,  Mannich reaction ,  polynuclear aromatic compound ,  cyclization reaction ,  enone ,  aromatic ketone ,  dimerization ,  *organic molecular catalyst ,  *super base ,  base catalysis ,  asymmetric organocatalysis ,  enantioselectivity ,  *Brook rearrangement ,  polarity conversion ,  diastereoselectivity ,  dithianes ,  thiolactone ,  Phenanthrenes ,  intramolecular cyclization ,  Chalcones
Semi thesaurus term： carbon-carbon bond ,  *C-C bond formation ,  [1,2]-ホスファ-ブルック転位 ,  nucleophilic reagent ,  dithiane derivatives ,  thiolactone derivatives ,  Mannich-type reaction ,  phenanthrene derivative ,  intramolecular cyclization reaction ,  Chalcones ,  dimerization

JST classification (5)： Catalytic reactions in general  (CB06080F) ,  Preparation of catalysts  (CB06110P) ,  Addition reaction,elimination reaction  (CF02030M) ,  Rearrangement reaction,isomerization  (CF02070E) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (10)： 1,3-Dithiane ,  3,3′-Dimethyl-7β,7′β,8α,8′α-tetraphenyl-1,1′,2,2′,7,7′,8,8′-octahydro-5,5′(6′H)-spirobi[3H-3,4,6,8a-tetraaza-5-phospha(V)-azulene] ,  Bis(guanidino)phosphorane ,  3,3′-Dibenzhydryl-7β,7′β,8α,8′α-tetraphenyl-2,2′,3,3′,7,7′,8,8′-octahydrospiro[1H-3,4,6,8a-tetraaza-5-phospha(V)azulene-5,5′(6′H)-[1H,5H-3,4,6,8a-tetraaza-5-phospha(V)]azulene] ,  2-((αS)-p-Methoxy-α-(Boc-amino)benzyl)-1,3-dithiane-2-carboxylic acid benzyl ester ,  2-((αS)-p-Bromo-α-(Boc-amino)benzyl)-1,3-dithiane-2-carboxylic acid benzyl ester ,  2-((S)-(2-Furyl)(Boc-amino)methyl)-1,3-dithiane-2-carboxylic acid benzyl ester ,  2-((S)-(2-Thienyl)(Boc-amino)methyl)-1,3-dithiane-2-carboxylic acid benzyl ester ,  Phosphoric acid diisopropyl α-[10-(ethoxycarbonyl)phenanthrene-9-yl]-4-nitrobenzyl ester ,  Phosphoric acid diethyl(3R,4S)-1,3,4,6-tetraphenyl-6-oxo-1-hexenyl ester

Reference (20)：

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Terms in the title (4)： 有機分子触媒 ,  超強塩基 ,  触媒 ,  炭素-炭素結合