Art

J-GLOBAL ID：201802250483552579   Reference number：18A1919081

The Gold-catalyzed Formal Hydration, Decarboxylation, and [4+2] Cycloaddition of Alkyne Derivatives Featuring L₂/Z-type Diphosphinoborane Ligands

L₂/Z型ジホスフィノボラン配位子を特徴とするアルキン誘導体の金触媒による形式的水和,脱炭酸および[4+2]環状付加

Author (5)： Matsumoto Chiaki (Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University) ,  Yamada Masayuki (Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University) ,  Dong Xun (Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University) ,  Mukai Chisato (Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University) ,  Inagaki Fuyuhiko (Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University)
Material： Chemistry Letters  (Chem Lett)
Volume： 47  Issue： 10  Page： 1321-1323(J-STAGE)  Publication year： 2018 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *cycloaddition ,  *transition metal catalyst ,  *gold complex ,  *phosphine complex ,  hydration ,  decarboxylation ,  *acetylenic compound ,  *boron complex ,  ligand effect ,  antimonate ,  fluoro acid ,  cyclization reaction
Semi thesaurus term： fluoroantimonate ,  *Au catalyst ,  intramolecular cyclization reaction

Author keywords (3)： Z-Ligand ,  Gold ,  Catalytic reaction

JST classification (4)： Complexes of 9 and 10 groups  (CE01050Y) ,  Nobel metal catalysts  (CB06122I) ,  Addition reaction,elimination reaction  (CF02030M) ,  Cyclization reaction,ring-opening reaction  (CF02050I)

Substance index (3)： Bis[2-(diphenylphosphino)phenyl]phenylborane ,  5,5-ビス(メトキシメチル)-9-メチル-8-デセン-2-イン酸 ,  6,6-bis(methoxymethyl)-1,1-dimethyl-5,7,8,8a-tetrahydroisochromen-3-one

Reference (61)：

• 1) M. L. H. Green, J. Organomet. Chem. 1995, 500, 127.
• 2) a) H. Braunschweig, R. D. Dewhurst, Dalton Trans. 2011, 40, 549.
• 2) b) A. Amgoune, D. Bourissou, Chem. Commun. 2011, 47, 859.
• 2) c) G. Bouhadir, D. Bourissou, Chem. Soc. Rev. 2016, 45, 1065.
• 3) a) D. L. M. Suess, J. C. Peters, J. Am. Chem. Soc. 2013, 135, 4938.

Terms in the title (7)： 配位子 ,  アルキン ,  誘導体 ,  金触媒 ,  水和 ,  脱炭酸 ,  環状付加