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J-GLOBAL ID：201802252323080352   Reference number：18A0005292

Diastereoselective Regiodivergent Mannich Versus Tandem Mannich-Cyclization Reactions

ジアステレオ選択的位置分岐的Mannich対タンデムMannich環化反応【Powered by NICT】

Author (13)： Zhang Wenzhong (School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, Nanjing University, 210093, People’s Republic of China) ,  Wang Xin (School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, Nanjing University, 210093, People’s Republic of China) ,  Zhu Biqing (School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, Nanjing University, 210093, People’s Republic of China) ,  Zhu Di (School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, Nanjing University, 210093, People’s Republic of China) ,  Han Jianlin (School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, Nanjing University, 210093, People’s Republic of China) ,  Wzorek Alicja (Department of Organic Chemistry I, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel Lardizabal 3, 20018, San Sebastian, Spain) ,  Wzorek Alicja (Institute of Chemistry, Jan Kochanowski University in Kielce, Swietokrzyska 15G, 25-406, Kielce, Poland) ,  Sato Azusa (Department of Organic Chemistry I, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel Lardizabal 3, 20018, San Sebastian, Spain) ,  Sato Azusa (School of Medicine, Tokyo Women’s Medical University, 8-1Kawada-cho, Shinjuku-ku, 1628666, Tokyo, Japan) ,  Soloshonok Vadim A. (Department of Organic Chemistry I, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel Lardizabal 3, 20018, San Sebastian, Spain) ,  Soloshonok Vadim A. (IKERBASQUE, Basque Foundation for Science Department Alameda Urquijo 36-5, Plaza Bizkaia, 48011, Bilbao, Spain) ,  Zhou Jie (School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, Nanjing University, 210093, People’s Republic of China) ,  Pan Yi (School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, Nanjing University, 210093, People’s Republic of China)
Material： Advanced Synthesis & Catalysis  (Adv Synth Catal)
Volume： 359  Issue： 24  Page： 4267-4273  Publication year： Dec. 2017 
JST Material Number： W1343A  ISSN： 1615-4150  CODEN： ASCAF7  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Abstract/Point： In the present work, we report...

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Thesaurus term： *stereoselectivity ,  diastereomer ,  selectivity ,  *Mannich reaction ,  *consecutive reaction ,  *cyclization reaction ,  sodium carbonate ,  substituent effect ,  *imine ,  *thiocyanogen ,  *ketone ,  reaction mechanism ,  spiro-compound ,  aromatic hydrocarbon ,  aliphatic carboxylic acid ,  carboxamide ,  cyclic ether ,  fatty acid ,  carboxylate(salt)
Semi thesaurus term： インダノン類 ,  *diastereofacial selectivity ,  *tandem reaction ,  location-selectivity

Author keywords (5)： Mannich additions ,  asymmetric synthesis ,  cascade reaction ,  aziridines ,  spirocycles

JST classification (1)： Addition reaction,elimination reaction  (CF02030M)

Substance index (6)： Dimethylformamide ,  Tetrahydrofuran ,  Acetic acid sodium ,  N-(tert-Butylsulfinyl)-2,2,2-trifluoroethaneimine ,  [(R)-2-[(S)-1-(tert-Butylsulfinylamino)-2,2,2-trifluoroethyl]-1-oxoindan-2-yl] thiocyanate ,  (2S)-1-(tert-Butylsulfinyl)-3-(trifluoromethyl)spiro[aziridine-2,2′-indan]-1′-one

Terms in the title (4)： ジアステレオ選択 ,  分岐 ,  タンデム ,  環化反応