Art

J-GLOBAL ID：201802255854810207   Reference number：18A0376891

Synthesis of Enol Esters through Silver-catalyzed or -mediated Hydroacyloxylation of Internal Alkynes

内部アルキンの銀を触媒に用いる,あるいは銀を媒介とするヒドロアシルオキシル化によるエノールエステルの合成

Author (4)： Kikui Nanae (Department of Chemistry, Graduate School of Science, Osaka City University) ,  Hinoue Tomoaki (Department of Chemistry, Graduate School of Science, Osaka City University) ,  Usuki Yoshinosuke (Department of Chemistry, Graduate School of Science, Osaka City University) ,  Satoh Tetsuya (Department of Chemistry, Graduate School of Science, Osaka City University)
Material： Chemistry Letters  (Chem Lett)
Volume： 47  Issue： 2  Page： 141-143(J-STAGE)  Publication year： 2018 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *acyloxylation ,  *enol ester ,  unsaturated carboxylic acid ,  aromatic carboxylic acid ,  *carboxylate (ester) ,  stereoselective reaction ,  structural isomer ,  addition reaction ,  reaction path ,  aliphatic carboxylic acid ,  X-ray structural analysis ,  silver catalyst ,  Benzoates ,  aromatic hydrocarbon ,  acetylenic compound ,  fatty acid
Semi thesaurus term： Benzoic Acids

Author keywords (3)： Silver catalyst ,  Hydroacyloxylation ,  Internal alkyne

JST classification (2)： Aliphatic carboxylic esters,anhydrides,acid halides,acyl peroxides  (CF03210P) ,  Catalytic reactions(homogeneous system)  (CB06090Q)

Substance index (18)： Diphenylacetylene ,  Pivalic acid ,  Silver(I) acetate ,  Pivalic acid (Z)-1,2-diphenylvinyl ester ,  Pivalic acid (Z)-1,2-bis(4-methylphenyl)vinyl ester ,  Pivalic acid (Z)-1,2-bis(4-chlorophenyl)vinyl ester ,  Pivalic acid (Z)-α-methylstyryl ester ,  Pivalic acid (Z)-α-butylstyryl ester ,  Pivalic acid (Z)-1-phenyl-1-propenyl ester ,  Pivalic acid (Z)-1-phenyl-1-hexenyl ester ,  (Z)-3-Phenyl-3-(pivaloyloxy)acrylic acid ethyl- ester ,  2,2-Dimethylbutanoic acid (Z)-1,2-diphenylvinyl ester ,  Adamantane-1-carboxylic acid (Z)-1,2-diphenylvinyl ester ,  Cyclohexanecarboxylic acid (Z)-1,2-diphenylvinyl ester ,  Methacrylic acid (Z)-1,2-diphenylvinyl ester ,  2-Methyl-2-butenoic acid (Z)-1,2-diphenylvinyl ester ,  Benzoic acid (Z)-1,2-diphenylvinyl ester ,  4-Methylbenzoic acid (Z)-1,2-diphenylvinyl ester

Reference (31)：

• 1) For selected reviews, see: a) J. Cornella, I. Larrosa, Synthesis 2012, 653.
• 1) b) N. Rodríguez, L. J. Goossen, Chem. Soc. Rev. 2011, 40, 5030.
• 1) c) T. Satoh, M. Miura, Synthesis 2010, 3395.
• 1) d) L. J. Gooßen, N. Rodríguez, K. Gooßen, Angew. Chem., Int. Ed. 2008, 47, 3100.
• 1) e) O. Baudoin, Angew. Chem., Int. Ed. 2007, 46, 1373.

Terms in the title (4)： 内部アルキン ,  銀 ,  触媒 ,  エノールエステル