Art
J-GLOBAL ID：201802262573821818   Reference number：18A1067505

An Efficient Synthesis of exo/endo-Hydroxylated Cyclohexenones by Thiol/Amine-Mediated Tandem Aldol-[2,3]-Sigmatropic Rearrangement: Amine-Dependent Complementary Regioselectivity

チオール/アミン媒介逐次アルドール-[2,3]-シグマトロピー転位によるexo/endo-ヒドロキシル化シクロヘキセノン類の効率的合成 アミン依存性相補的位置選択性【JST・京大機械翻訳】
Author (5)：
Miura Motofumi

About Miura Motofumi

(School of Pharmacy, Nihon University, 7-7-1 Narashinodai, Funabashi-shi, Chiba, 274-8555, Japan)

About School of Pharmacy, Nihon University, 7-7-1 Narashinodai, Funabashi-shi, Chiba, 274-8555, Japan

, 
Nakakita Toshinori

About Nakakita Toshinori

(School of Pharmacy, Nihon University, 7-7-1 Narashinodai, Funabashi-shi, Chiba, 274-8555, Japan)

About School of Pharmacy, Nihon University, 7-7-1 Narashinodai, Funabashi-shi, Chiba, 274-8555, Japan

, 
Nakakita Toshinori

About Nakakita Toshinori

(Faculty of Pharmaceutical Science, Aomori University, 2-3-1 Kobato, Aomori-shi, Aomori, 030-0943, Japan)

About Faculty of Pharmaceutical Science, Aomori University, 2-3-1 Kobato, Aomori-shi, Aomori, 030-0943, Japan

, 
Toriyama Masaharu

About Toriyama Masaharu

(School of Pharmacy, Nihon University, 7-7-1 Narashinodai, Funabashi-shi, Chiba, 274-8555, Japan)

About School of Pharmacy, Nihon University, 7-7-1 Narashinodai, Funabashi-shi, Chiba, 274-8555, Japan

, 
Motohashi Shigeyasu

About Motohashi Shigeyasu

(School of Pharmacy, Nihon University, 7-7-1 Narashinodai, Funabashi-shi, Chiba, 274-8555, Japan)

About School of Pharmacy, Nihon University, 7-7-1 Narashinodai, Funabashi-shi, Chiba, 274-8555, Japan


Material：
Asian Journal of Organic Chemistry

About Asian Journal of Organic Chemistry


Volume： 7  Issue： 5  Page： 883-887  Publication year： 2018 
JST Material Number： W2500A  ISSN： 2193-5807  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)
Abstract/Point：
Abstract/Point
Japanese summary of the article(about several hundred characters).
All summary is available on JDreamIII(charged).
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exo/endo-Hydroxylated cyclohex...
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Thesaurus term：
Thesaurus term/Semi thesaurus term
Keywords indexed to the article.
All keywords is available on JDreamIII(charged).
On J-GLOBAL, this item will be available after more than half a year after the record posted. In addtion, medical articles require to login to MyJ-GLOBAL.
*sigmatropy

About sigmatropy

, 
stereoisomer

About stereoisomer

, 
synthetic intermediate

About synthetic intermediate

, 
hydrogenation

About hydrogenation

, 
*xenon

About xenon

, 
*hydroxylation

About hydroxylation

, 
natural material

About natural material


Semi thesaurus term：
Thesaurus term/Semi thesaurus term
Keywords indexed to the article.
All keywords is available on JDreamIII(charged).
On J-GLOBAL, this item will be available after more than half a year after the record posted. In addtion, medical articles require to login to MyJ-GLOBAL.
反応条件

About 反応条件

, 
レギオ選択性

About レギオ選択性

, 【Automatic Indexing@JST】
Author keywords (5)：
allylic compounds

About allylic compounds

, 
amines

About amines

, 
natural products

About natural products

, 
regioselectivity

About regioselectivity

, 
sigmatropic rearrangement

About sigmatropic rearrangement

JST classification (4)：
JST classification
Category name(code) classified by JST.
Regiochemistry of organic reaction 
(CF02140G)

About Regiochemistry of organic reaction

,  Condensed derivatives of pyrane 
(CF07093I)

About Condensed derivatives of pyrane

,  Cyclization reaction,ring-opening reaction 
(CF02050I)

About Cyclization reaction,ring-opening reaction

,  Stereochemistry of organic reaction 
(CF02130V)

About Stereochemistry of organic reaction

Terms in the title (8)：
Terms in the title
Keywords automatically extracted from the title.
チオール

About チオール

, 
アミン

About アミン

, 
逐次

About 逐次

, 
アルドール

About アルドール

, 
シグマトロピー転位

About シグマトロピー転位

, 
ヒドロキシル化

About ヒドロキシル化

, 
依存性

About 依存性

, 
位置選択性

About 位置選択性


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