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J-GLOBAL ID：201802263214298732   Reference number：18A1073633

Synthesis of Isotactic-block-Syndiotactic Poly(methyl Methacrylate) via Stereospecific Living Anionic Polymerizations in Combination with Metal-Halogen Exchange, Halogenation, and Click Reactions

金属-ハロゲン交換,ハロゲン化およびクリック反応と組み合わせた立体特異的リビングアニオン重合によるイソタクチック-block-チックポリメタクリル酸メチルの合成【JST・京大機械翻訳】

Author (4)： Usuki Naoya (Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan) ,  Satoh Kotaro (Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan) ,  Satoh Kotaro (Precursory Research for Embryonic Science and Technology, Japan Science and Technology Agency, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan) ,  Kamigaito Masami (Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan)
Material： Polymers (Web)
Volume： 9  Issue： 12  Page： 723  Publication year： 2017 
JST Material Number： U7262A  ISSN： 2073-4360  Document type： Article
Article type： 原著論文  Country of issue： Switzerland (CHE)  Language： ENGLISH (EN)

Abstract/Point： Isotactic (it-) and syndiotact...

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Thesaurus term： *anionic polymerization ,  cycloaddition ,  azide (organic) ,  complex formation ,  complex (compound) ,  alkyne ,  polymer ,  *Halogenation ,  copper catalyst ,  stereospecific polymerization ,  *living anion polymerization ,  Molecular Weight ,  *isotactic ,  *Click Chemistry ,  alkylbenzene

Author keywords (10)： living polymerization ,  stereospecific polymerization ,  anionic polymerization ,  methyl methacrylate ,  PMMA ,  stereoblock polymer ,  stereocomplex ,  click reaction ,  isotactic polymer ,  syndiotactic polymer

JST classification (3)： Polymerization catalyst,polymerization initiator  (CG04070V) ,  Homopolymerization  (CG04020S) ,  Structure and morphology of polymer solids  (CG02022M)

Substance index (1)： Toluene

Reference (52)：

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• Fox, T.G.; Garrett, B.S.; Goode, W.E.; Gratch, S.; Kincaid, J.F.; Spell, A.; Stroupe, J.D. Crystalline polymers of methyl methacryalte. J. Am. Chem. Soc. 1958, 80, 1768-1769.
• Liquori, A.M.; Anzuino, G.; Coiro, V.M.; D’Alagni, M.; De Santis, P.; Savino, M. Complementary stereospecific interaction between isotactic and syndiotactic polymer molecules. Nature 1965, 206, 358-362.
• Schomaker, E.; Challa, G. Complexation of stereoregular poly(methyl methacryalte). 14. The basic structure of the stereocomplex of isotactic and syndiotactic poly(methyl methacryalte). Macromolecules 1989, 22, 3337-3341.

Terms in the title (7)： ハロゲン ,  ハロゲン化 ,  クリック反応 ,  リビングアニオン重合 ,  イソタクチック ,  チック ,  ポリメタクリル酸メチル