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J-GLOBAL ID：201802269525315468   Reference number：18A0153959

Synthesis and reactivity of [M(η³-allyl)(η²-amidinato)(CO)₂(phosphonium ylide)] (M = Mo, W): Investigation of the ligand properties of phosphonium ylides

[M(η~3-アリル)(η~2-amidinato)(CO)_2(ホスホニウムイリド)](M=Mo, W)の合成と反応性ホスホニウムイリドの配位子特性の研究【Powered by NICT】

Author (6)： Takaki Daichi (Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan) ,  Ogata Kenichi (Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan) ,  Kurihara Youji (Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan) ,  Ueda Kazuyoshi (Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan) ,  Hashimoto Toru (Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan) ,  Yamaguchi Yoshitaka (Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan)
Material： Inorganica Chimica Acta  (Inorg Chim Acta)
Volume： 471  Page： 310-315  Publication year： 2018 
JST Material Number： D0620A  ISSN： 0020-1693  Document type： Article
Article type： 原著論文  Country of issue： Netherlands (NLD)  Language： ENGLISH (EN)

Abstract/Point： Phosphonium ylide complexes of...

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Thesaurus term： density functional method ,  *reactivity ,  characterization ,  heterocyclic compound ,  *molybdenum ,  *ylide ,  complex(compound) ,  carbene ,  X-ray diffraction ,  substitution reaction
Semi thesaurus term： 置換基 ,  電子供与体 ,  ホスフィン配位子 ,  分光学 ,  *ホスホニウムイリド , 【Automatic Indexing@JST】

Author keywords (4)： Phosphonium ylide ,  Electron donating ability ,  Bond strength ,  DFT calculations

JST classification (2)： 6A and 7A groups  (CE01080F) ,  Crystal structure of complex of transition metals(excluding iron group)  (BK09030X)

Terms in the title (6)： アリル ,  CO ,  ホスホニウムイリド ,  反応性 ,  配位子 ,  研究