Art

J-GLOBAL ID：201802279305573193   Reference number：18A0311217

Novel Transformations Utilizing [1,2]-Phospha-Brook Rearrangement Under Bronsted Base Catalysis

ブレンステッド塩基触媒による[1,2]-ホスファ-ブルック転位を利用した新たな分子変換反応

Author (2)： KONDO AZUSA (東北大 大学院理学研究科 巨大分子解析研究セ) ,  TERADA MASAHIRO (東北大 大学院理学研究科)
Material： 有機合成化学協会誌  (Journal of Synthetic Organic Chemistry, Japan)
Volume： 76  Issue： 2  Page： 151-163  Publication year： Feb. 01, 2018 
JST Material Number： F0383A  ISSN： 0037-9980  CODEN： YGKKAE  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： JAPANESE (JA)

Thesaurus term： chemical synthesis ,  base catalytic reaction ,  *rearrangement reaction ,  consecutive reaction ,  reversal ,  C-C bond ,  oxygen heterocyclic compound ,  nitrogen heterocyclic compound ,  *carbanion ,  addition reaction ,  protonation ,  isomerization ,  cyclization reaction ,  Wittig rearrangement ,  organophosphorus compound ,  *phosphorus oxyacid ,  Broensted base ,  *Brook rearrangement ,  tandem reaction ,  cycloisomerization ,  polarity inversion ,  Indolizines ,  Furans ,  *Phosphoric Acid Esters ,  aromatic ketone ,  enone
Semi thesaurus term： C-C bond formation ,  Indolizines ,  furans ,  *Phosphoric Acid Esters

JST classification (2)： Organop phosphorus compounds  (CF08040N) ,  Catalytic reactions in general  (CB06080F)

Substance index (19)： (2R,3S)-2,3-Diphenyl-3-(tosylamino)-2-(diethoxyphosphinoyloxy)propionic acid benzyl ester ,  (2S,3R)-2-(Diethoxyphosphinoyloxy)-4-nitro-2,3-diphenylbutanoic acid benzyl ester ,  2-Pyridyl(1-hexynyl) ketone ,  Phosphoric acid diisopropyl α-[10-(ethoxycarbonyl)phenanthrene-9-yl]-4-nitrobenzyl ester ,  Di(dimethylamino)(tert-butylimino)(tri(dimethylamino)phosphinediylamino)phosphine ,  N-Tosylbenzenemethanimine ,  N-Benzyl-N-(2-ethynylphenyl)-α-oxo-4-methoxybenzeneacetamide ,  N-Benzyl-N-phenyl-2-oxo-3-octyneamide ,  α-Oxo-2′-(4-nitrophenylethynyl)biphenyl-2-acetic acid ethyl ester ,  Phenyloxoacetic acid benzyl ester ,  β-Nitrostyrene ,  Chalcone ,  Phosphonic acid diethyl ,  Phosphoric acid diethyl[(1Z,3R,4S)-1,3,4,6-tetraphenyl-6-oxo-1-hexenyl] ester ,  Phosphoric acid diethyl 1-benzyl-2-oxo-3-phenyl-1,2-dihydroquinoline-4-ylmethyl ester ,  N-Benzyl-N-phenyl-2-(diethoxyphosphinyloxy)-2,3-octeneamide ,  Phosphoric acid diethyl[1-benzyl-2-oxo-3-(4-methoxyphenyl)-4-methylene-1,2,3,4-tetrahydroquinoline-3-yl] ester ,  5-Butyl-3-(diethoxyphosphinyloxy)-N-benzyl-N-phenyl-2-furanamine ,  Phosphoric acid diethyl 3-butylindolizine-1-yl ester

Reference (67)：

• 1) For early studies, see: (a) S. J. Fitch, K. Moedritzer, J. Am. Chem. Soc., 84, 1876 (1962)
• (b) L. A. R. Hall, C. W. Stephenes, J. J. Drysdals, J. Am. Chem. Soc., 79, 1768 (1957)
• (c) W. F. Barthel, B. H. Alexander, P. A. Giang, S. A. Hall, J. Am. Chem. Soc., 77, 2424 (1955)
• (d) A. M. Mattson, J. T. Spillane, G. W. Pearce, J. Agric. Food Chem., 3, 319 (1955)
• (e) W. Lorenz, A. Henglbin, G. Schrader, J. Am. Chem. Soc., 77, 2554 (1955)

Terms in the title (5)： ブレンステッド塩基 ,  触媒 ,  ブルック転位 ,  分子 ,  変換反応