Art

J-GLOBAL ID：201802279654033400   Reference number：18A1611046

Steric Course of Deprotonation/Substitution of Chelating/Dipole-Stabilizing-Group-Substituted α-Amino- and α-Oxynitriles

キレート化/双極子安定化基置換α-アミノ-およびα-oxynitrの脱プロトン/置換の立体過程【JST・京大機械翻訳】

Author (6)： Sasaki Michiko (Department of Synthetic Organic Chemistry, Institute of Biomedical & Health Science, Hiroshima University, 1-2-3 Kasumi, 734-8553, Minami-Ku, Hiroshima, Japan) ,  Shimabara Rumiko (Department of Synthetic Organic Chemistry, Institute of Biomedical & Health Science, Hiroshima University, 1-2-3 Kasumi, 734-8553, Minami-Ku, Hiroshima, Japan) ,  Takegawa Tomo (Department of Synthetic Organic Chemistry, Institute of Biomedical & Health Science, Hiroshima University, 1-2-3 Kasumi, 734-8553, Minami-Ku, Hiroshima, Japan) ,  Kotomori Yuri (Department of Synthetic Organic Chemistry, Institute of Biomedical & Health Science, Hiroshima University, 1-2-3 Kasumi, 734-8553, Minami-Ku, Hiroshima, Japan) ,  Otani Yuko (Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, 113-0033, Bunkyo-Ku, Tokyo, Japan) ,  Ohwada Tomohiko (Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, 113-0033, Bunkyo-Ku, Tokyo, Japan)
Material： European Journal of Organic Chemistry  (Eur J Org Chem)
Volume： 2018  Issue： 30  Page： 4128-4134  Publication year： 2018 
JST Material Number： W1026A  ISSN： 1434-193X  CODEN： EJOCFK  Document type： Article
Article type： 原著論文  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Abstract/Point： The stereochemical course of e...

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Thesaurus term： carbanion ,  asymmetric synthesis ,  nitrile ,  Lithium ,  anion ,  reactivity ,  electrophilic substitution reaction ,  *dipole ,  *deprotonation ,  *chelation ,  chirality ,  substituent ,  electrophilicity
Semi thesaurus term： 富化 , 【Automatic Indexing@JST】

Author keywords (5)： Asymmetric synthesis ,  Carbanions ,  Chirality ,  Electrophilic substitution ,  Nitriles

JST classification (1)： Aliphatic nitriles,isocyanides  (CF03230L)

Substance index (1)： Hexamethyldisilazane

Terms in the title (7)： キレート化 ,  双極子 ,  安定化 ,  置換 ,  脱プロトン ,  立体 ,  過程