Art

J-GLOBAL ID：201802297775755445   Reference number：18A1758263

Formation of Metal-coordinated Doubly Chelating Pentadentate Ligands by the Reactions of [MoH₄(Ph₂PCH₂CH₂PPh₂)₂] with Organohydrodisilanes

有機ヒドロジシランと[MoH₄(Ph₂PCH₂CH₂PPh₂)₂]の反応による金属配位二重キレート五座配位子の生成

Author (4)： Minato Makoto (Department of Materials Chemistry, Faculty of Engineering, Yokohama National University) ,  Nanami Toshiki (Department of Materials Chemistry, Faculty of Engineering, Yokohama National University) ,  Kogoma Kenzi (Department of Materials Chemistry, Faculty of Engineering, Yokohama National University) ,  Ito Takashi (Department of Materials Chemistry, Faculty of Engineering, Yokohama National University)
Material： Chemistry Letters  (Chem Lett)
Volume： 47  Issue： 9  Page： 1105-1107(J-STAGE)  Publication year： 2018 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *molybdenum complex ,  *phosphine complex ,  chelate compound ,  ligand ,  hydrido complex ,  organosilicon compound ,  cleavage reaction ,  addition reaction ,  thermochemical reaction ,  *silyl complex ,  oxidative addition ,  aromatic compound ,  organophosphorus compound
Semi thesaurus term： bond cleavage reaction ,  oxidative addition reaction

Author keywords (3)： Molybdenum ,  Silyl ligand ,  Trans influence

JST classification (2)： 6A and 7A groups  (CE01080F) ,  Organosilicon compounds  (CF08030C)

Substance index (2)： Ethylenebis(diphenylphosphine) ,  2-メチル-2-[ビス[2-(メチルフェニルホスフィノ)フェニル]シリル]プロパン

Reference (30)：

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• 1) b) T. D. Tilley, in <i>The Silicon-Heteroatom Bond</i>, ed. by S. Patai, Z. Rapport, John Wiley & Sons, New York, <b>1991</b>, Ch. 10. doi:10.1002/9780470772447.ch10.
• 1) c) J. Y. Corey, J. Braddock-Wilking, Chem. Rev. 1999, 99, 175.
• 1) d) J. Takaya, N. Iwasawa, J. Am. Chem. Soc. 2008, 130, 15254.
• 1) e) M. C. MacInnis, R. McDonald, M. J. Ferguson, S. Tobisch, L. Turculet, J. Am. Chem. Soc. 2011, 133, 13622.

Terms in the title (2)： キレート ,  配位子