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J-GLOBAL ID：201902235172287577   Reference number：19A2413178

Nickel-Catalyzed [5+2] Cycloaddition of 10π-Electron Aromatic Benzothiophenes with Alkynes To Form Thermally Metastable 12π-Electron Nonaromatic Benzothiepines

10π-Electron芳香族ベンゾチオフェン類とアルキン類のニッケル触媒[5+2]環状付加による熱的に準安定な12π-Electron非芳香族ベンゾチアゾリン類の生成【JST・京大機械翻訳】

Author (4)： Inami Tasuku (Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Japan) ,  Takahashi Toshifumi (Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Japan) ,  Kurahashi Takuya (Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Japan) ,  Matsubara Seijiro (Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Japan)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 141  Issue： 32  Page： 12541-12544  Publication year： 2019 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Abstract/Point： The nickel-catalyzed formal [5...

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Thesaurus term： intermediate ,  ring enlargement reaction ,  sulfur ,  *alkyne ,  XAFS ,  *nickel catalyst ,  *cycloaddition ,  heterocyclic compound ,  sulfur heterocyclic compound ,  polynuclear aromatic compound
Semi thesaurus term： 密度汎関数計算 ,  酸化的付加 ,  C-S結合 ,  脱芳香族化 , 【Automatic Indexing@JST】

JST classification (5)： Cyclization reaction,ring-opening reaction  (CF02050I) ,  Alkenes  (CF03030T) ,  Catalytic reactions in general  (CB06080F) ,  Aliphatic aldehydes  (CF03180F) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (1)： Benzothiophene

Terms in the title (5)： π ,  芳香族 ,  ベンゾチオフェン類 ,  ニッケル触媒 ,  環状付加