Art

J-GLOBAL ID：201902235463804171   Reference number：19A2650023

Diastereoselective Methylation at the Congested β-Position of a Butenolide Ring: Studies toward the Synthesis of seco-Prezizaane-Type Sesquiterpenes

ブテノリド環の混雑したβ位におけるジアステレオ選択的メチル化 セコ-プレジザアン型セスキテルペンの合成に向けた研究【JST・京大機械翻訳】

Author (4)： Kawamura Tomoyoshi (Department of Basic Medicinal Sciences, Graduate School of Pharmaceutical Sciences, Nagoya University, Japan) ,  Moriya Hirokazu (Department of Basic Medicinal Sciences, Graduate School of Pharmaceutical Sciences, Nagoya University, Japan) ,  Shibuya Masatoshi (Department of Basic Medicinal Sciences, Graduate School of Pharmaceutical Sciences, Nagoya University, Japan) ,  Yamamoto Yoshihiko (Department of Basic Medicinal Sciences, Graduate School of Pharmaceutical Sciences, Nagoya University, Japan)
Material： Journal of Organic Chemistry  (J Org Chem)
Volume： 84  Issue： 19  Page： 12508-12519  Publication year： 2019 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Abstract/Point： We established a method for in...

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Thesaurus term： *Methylation ,  fluoride ,  oxidation ,  deoxidization ,  C-C bond ,  silyl ether ,  cyclic ,  conjugated addition ,  Nerve ,  methyl group ,  *diastereoselectivity ,  *butenolide derivative

JST classification (4)： Addition reaction,elimination reaction  (CF02030M) ,  Aliphatic carboxylic esters,anhydrides,acid halides,acyl peroxides  (CF03210P) ,  Cyclization reaction,ring-opening reaction  (CF02050I) ,  Furans  (CF07072V)

Terms in the title (6)： ブテノリド ,  環 ,  ジアステレオ選択 ,  メチル化 ,  セスキテルペン ,  研究