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J-GLOBAL ID：201902242856825610   Reference number：19A1406804

Carbon Kinetic Isotope Effects and the Mechanisms of Acid-Catalyzed Decarboxylation of 2,4-Dimethoxybenzoic Acid and CO₂ Incorporation into 1,3-Dimethoxybenzene

1,3-ジメトキシベンゼンへの2,4-ジメトキシ安息香酸とCO_2の取り込みの炭素速度論的同位体効果と酸触媒脱炭酸の機構【JST・京大機械翻訳】

Author (4)： Vandersteen Adelle A. (Davenport Chemical Research Laboratories, Department of Chemistry and The Stable Isotopes Laboratory, University of Toronto) ,  Howe Graeme W. (Davenport Chemical Research Laboratories, Department of Chemistry and The Stable Isotopes Laboratory, University of Toronto) ,  Sherwood Lollar Barbara (Department of Earth Sciences, University of Toronto) ,  Kluger Ronald (Davenport Chemical Research Laboratories, Department of Chemistry and The Stable Isotopes Laboratory, University of Toronto)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 139  Issue： 42  Page： 15049-15053  Publication year： Oct. 25, 2017 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Abstract/Point： The rate of decarboxylation of...

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Thesaurus term： cleavage reaction ,  proton ,  reversibility ,  protonation ,  oxygen ,  rate-limiting ,  *rate theory ,  decarboxylation reaction ,  conjugation ,  proton shift ,  *carbon ,  carbon dioxide
Semi thesaurus term： *酸触媒 , 【Automatic Indexing@JST】

JST classification (3)： Catalytic reactions(homogeneous system)  (CB06090Q) ,  Addition reaction,elimination reaction  (CF02030M) ,  Catalytic reactions(heterogeneous system)  (CB06100E)

Substance index (2)： 2,4-Dimethoxybenzoic acid ,  1,3-Dimethoxybenzene

Terms in the title (6)： 安息香酸 ,  取り込み ,  炭素 ,  速度論的同位体効果 ,  酸触媒 ,  脱炭酸