Art

J-GLOBAL ID：201902245736925914   Reference number：19A0589656

Iron-Indium Complex Catalyzing Selective Double Hydrosilylation, Double Hydroborylation, and Dihydroborylsilylation of a C≡N Bond in Organonitriles

新規な鉄-インジウム錯体を触媒とする有機ニトリル化合物のC≡N結合への選択的なダブルヒドロシリル化,ダブルヒドロボリル化およびジヒドロボリルシリル化反応

Author (2)： ITAZAKI MASUMI (大阪市大 大学院理学研究科) ,  NAKAZAWA HIROSHI (大阪市大 大学院理学研究科)
Material： 有機合成化学協会誌  (Journal of Synthetic Organic Chemistry, Japan)
Volume： 77  Issue： 3  Page： 220-226  Publication year： Mar. 01, 2019 
JST Material Number： F0383A  ISSN： 0037-9980  CODEN： YGKKAE  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： JAPANESE (JA)

Thesaurus term： catalytic reaction ,  iron complex ,  indium complex ,  ruthenium complex ,  *nitrile ,  *hydrosilylation ,  *hydroboration ,  organosilicon compound ,  organoboron compound ,  tertiary amine ,  one-pot synthesis ,  reaction mechanism ,  aliphatic nitrile

JST classification (2)： Aliphatic nitriles,isocyanides  (CF03230L) ,  Catalytic reactions in general  (CB06080F)

Substance index (18)： 2,2′-Isobutyliminobis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) ,  N,N-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborole-2-yl)isopentylamine ,  2,2′-(o-Methylbenzyl)iminobis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) ,  N,N-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborole-2-yl)ethylamine ,  Bis(dimethylphenylsilyl)(4-methylbenzyl)amine ,  Bis(dimethylphenylsilyl)benzylamine ,  Bis(methylphenylsilyl)ethylamine ,  N-(4,4,5,5-Tetramethyl-1,3,2-dioxaborole-2-yl)-N-(phenyldimethylsilyl)ethylamine ,  Acetonitrile ,  Di(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)4-methylbenzylamine ,  Di(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)phenethylamine ,  Di(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)benzylamine ,  Bis(dimethylphenylsilyl)isobutylamine ,  Bis(dimethylphenylsilyl)isopentylamine ,  Bis(dimethylphenylsilyl)ethylamine ,  N,N-Bis(phenyldimethylsilyl)-1-propaneamine ,  Pinacolborane ,  Phenyldimethylsilane

Reference (58)：

• 1) References cited therein: (a) M. Birot, J.-P. Pillot, J. Dunogues, Chem. Rev., 95, 1443 (1995)
• (b) P. Colombo, G. Mera, R. Riedel, G. D. Sorarù, J. Am. Ceram. Soc., 93, 1805 (2010)
• (c) L. Meng, X. Zhang, Y. Tang, K. Su, J. Kong, Sci. Rep., 5, 7910 (2015)
• (d) A. Viard, P. Miele, S. Bernard, J. Ceram. Soc. Jpn., 124, 967 (2016)
• 2) (a) M. Jansen, T. Jäschke, Z. Naturforsch., B: J. Chem. Sci., 55, 763 (2000)

Terms in the title (6)： 鉄 ,  インジウム錯体 ,  触媒 ,  ニトリル化合物 ,  N結合 ,  ヒドロシリル化