Art

J-GLOBAL ID：201902248329002465   Reference number：19A2689961

天然物のNMR研究-立体化学決定および溶液中と膜中における配座解析

Author (1)： MATSUMORI NOBUAKI (九大)
Material： NMR (Web)  (NMR学会誌(Web))
Volume： 10  Page： 76-81 (WEB ONLY)  Publication year： Nov. 05, 2019 
JST Material Number： U0731A  Document type： Article
Article type： 解説  Country of issue： Japan (JPN)  Language： JAPANESE (JA)

Thesaurus term： *NMR ,  *natural material ,  *conformational analysis ,  stereochemistry ,  Carbon ,  optical isomerism ,  dynamic characteristic ,  methodology ,  lipid membrane ,  steric conformation ,  space structure ,  sphingomyelin ,  chain structure ,  asymmetric carbon ,  polyene ,  sterol ,  alicyclic alcohol ,  secondary alcohol
Semi thesaurus term： dynamic behaviour

JST classification (1)： NMR of organic compounds  (BM07044Q)

Substance index (3)： Amphotericin B ,  Amphidinol 3 ,  Ergosterol

Reference (16)：

• Matsumori N, Murata M. (2017) NMR studies on natural product - Stereochemical determination and conformational analysis in solution and in membrane. Experimental Approaches of NMR Spectroscopy (Springer) pp 383-414.
• Matsumori N, Kaneno D, Murata M, Nakamura H, Tachibana K. (1999) Stereochemical determination of acyclic structures based on carbon-proton spin-coupling constants. A method of configuration analysis for natural products. J Org Chem 64, 866-876.
• 岩下孝、楠見武徳、村田道雄(2012)「NMR立体化学」講談社
• (a) Sasaki M, Matsumori N, Maruyama T, Nonomura T, Murata M, Tachibana K, Yasumoto T. (1996) The complete structure of maitotoxin 1. Configuration of the C1-C14 side chain. Angew. Chem. Int. Ed. 35, 1672-1675. (b) Nonomura T, Sasaki M, Matsumori N, Murata M, Tachibana K, Yasumoto T. (1996) The complete structure of maitotoxin 2. Configuration of the C135-C142 side chain and absolute configuration of the entire molecule Angew. Chem. Int. Ed. 35, 1675-1678. (c) Matsumori N, Nonomura T, Sasaki M, Murata M, Tachibana K, Satake M, Yasumoto T. (1996) Longrange carbon-proton coupling constants for stereochemical assignment of acyclic structures in natural products: Configuration of the C5-C9 portion of maitotoxin. Tetrahedron Lett. 37, 1269-1272.
• Murata M, Matsuoka S, Matsumori N, Paul G.K, Tachibana K. (1999) Absolute configuration of amphidinol 3, the first complete structure determination from amphidinol homologues: Application of a new configuration analysis based on carbonhydrogen spin-coupling constants. J. Am. Chem. Soc. 121, 870-871.

Terms in the title (6)： 天然物 ,  NMR ,  研究 ,  立体化学 ,  溶液 ,  配座解析