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J-GLOBAL ID：201902250552738638   Reference number：19A0968403

Chiral Tectonics: VCD and ECD Application for Epimerization of a Star-Burst Tetranuclear Complex with a Labile Central Core

キラルテクトニクス 不安定中心コアを持つ星-バースト四核錯体のエピマー化のためのVCDおよびECD応用【JST・京大機械翻訳】

Author (3)： Sato Hisako (Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577, Japan) ,  Sato Fumi (Department of Medicine, Toho University, Tokyo 143-8540, Japan) ,  Yamagishi Akihiko (Department of Medicine, Toho University, Tokyo 143-8540, Japan)
Material： Inorganics (Web)
Volume： 6  Issue： 3  Page： 70  Publication year： 2018 
JST Material Number： U7205A  ISSN： 2304-6740  Document type： Article
Article type： 原著論文  Country of issue： Switzerland (CHE)  Language： ENGLISH (EN)

Abstract/Point： The present article reports th...

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Thesaurus term： *epimerization ,  temperature dependence ,  absolute configuration ,  *complex (compound) ,  spectrum ,  *burst ,  enantiomer ,  metal complex ,  Chromatography ,  mutual transformation ,  *tectonics ,  activation energy ,  *tetranuclear complex ,  *chirality
Semi thesaurus term： 電子円偏光二色性 , 【Automatic Indexing@JST】

Author keywords (10)： vibrational circular dichroism ,  temperature-dependent electronic circular dichroism ,  epimerization ,  tetranuclear complex ,  β-diketonato ,  Ru(III) ,  Al(III) ,  chiral ,  ΔΛ isomers ,  chiral tectons

JST classification (1)： Platinum family element complexes  (CE01100E)

Reference (26)：

• Amouri, H.; Gruselle, M. Chirality in Transion Metal Chemsitry; Wiley: West Sussex, UK, 2008; pp. 121-232.
• Riehl, J.P.; Kaizaki, S. Absolute Chiral Structures of Inorganic Compounds. In Physical Inorganic Chemistry; Bakac, A., Ed.; Wiley: Hoboken, NJ, USA, 2010; pp. 143-197.
• Brock, A.J.; Clegg, J.K.; Li, F.; Lindoy, L.F. Recent developments in the metallo-supramolecular chemistry of oligo-β-diketonato ligands. Coord. Chem. Rev. 2018.
• Jędrzejewska, H.; Szumna, A. Making a Right or Left Choice: Chiral Self-Sorting as a Tool for the Formation of Discrete Complex Structures. Chem. Rev. 2017, 117, 4863-4899.
• Sato, H.; Yamagishi, A. Application of the ∆Λ Isomerism of Octahedral Metal Complexes as a Chiral Source in Photochemistry. J. Photochem. Photobiol. C Photochem. Rev. 2007, 8, 67-84.

Terms in the title (8)： 中心コア ,  星 ,  バースト ,  四核錯体 ,  エピマー化 ,  VCD ,  ECD ,  応用