Art

J-GLOBAL ID：201902251682056575   Reference number：19A0917038

New Insights on the Oxidation of Unsaturated Fatty Acid Methyl Esters Catalyzed by Niobium(V) Oxide. A Study of the Catalyst Surface Reactivity

ニオブ(V)酸化物触媒による不飽和脂肪酸メチルエステルの酸化に関する新しい洞察 触媒表面反応性の研究【JST・京大機械翻訳】

Author (6)： Cecchi Christian Marcelo Paraguassu (Instituto Federal Fluminense (IFF), Campus: Campos-Centro, Campos dos Goytacazes 28030-130, Brazil) ,  Cecchi Christian Marcelo Paraguassu (Departamento de Quimica, ICE, Universidade Federal Rural do Rio de Janeiro (UFRRJ), BR-465, Km 7, Seropedica 23897-000, Brazil) ,  Cesarin-Sobrinho Dari (Departamento de Quimica, ICE, Universidade Federal Rural do Rio de Janeiro (UFRRJ), BR-465, Km 7, Seropedica 23897-000, Brazil) ,  Ferreira Aurelio Baird Buarque (Departamento de Quimica, ICE, Universidade Federal Rural do Rio de Janeiro (UFRRJ), BR-465, Km 7, Seropedica 23897-000, Brazil) ,  Netto-Ferreira Jose Carlos (Departamento de Quimica, ICE, Universidade Federal Rural do Rio de Janeiro (UFRRJ), BR-465, Km 7, Seropedica 23897-000, Brazil) ,  Netto-Ferreira Jose Carlos (Divisao de Metrologia Quimica, Instituto Nacional de Metrologia, Qualidade e Tecnologia (INMETRO), Duque de Caxias 25250-020, Brazil)
Material： Catalysts (Web)
Volume： 8  Issue： 1  Page： 6  Publication year： 2018 
JST Material Number： U7154A  ISSN： 2073-4344  Document type： Article
Article type： 原著論文  Country of issue： Switzerland (CHE)  Language： ENGLISH (EN)

Abstract/Point： The catalytic properties of ni...

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Thesaurus term： high speed ,  *reactivity ,  *catalyst ,  *oxidation ,  probe ,  hydrogen peroxide ,  characterization ,  aldehyde ,  amorphous state ,  diffuse reflection ,  crystallization ,  autoxidation ,  reaction mechanism ,  aliphatic alcohol ,  unsaturated fatty acid ,  diene ,  carboxylate(ester)
Semi thesaurus term： ヒドロペルオキシド , 【Automatic Indexing@JST】

Author keywords (7)： Nb₂O₅ ,  H₂O₂ ,  methyl linoleate ,  Raman spectroscopy ,  oxidation ,  9-oxo-nonanoic acid methyl ester ,  hock rearrangement

JST classification (4)： Enzyme in general  (EB09010D) ,  Gene manipulation  (EC02050B) ,  Other catalysts  (CB06123Z) ,  Applications of enzymes  (EB09100B)

Substance index (1)： Linoleic acid methyl ester

Reference (88)：

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• Nakajima, K.; Baba, Y.; Noma, R.; Kitano, M.; Kondo, J.N.; Hayashi, S.; Hara, M. Nb2O5·nH2O as a Heterogeneous Catalyst with Water-Tolerant Lewis Acid Sites. J. Am. Chem. Soc. 2011, 133, 4224-4227.
• Nico, C.; Monteiro, T.; Graça, M.P.F. Niobium oxides and niobates physical properties: Review and prospects. Prog. Mater. Sci. 2016, 80, 1-37.
• Valencia-Balvín, C.; Pérez-Walton, S.; Dalpian, G.M.; Osorio-Guillén, J.M. First-principles equation of state and phase stability of niobium pentoxide. Comp. Mater. Sci. 2014, 81, 133-140.
• Aleshina, L.A.; Malinenko, V.P.; Phouphanov, A.D.; Jakovleva, N.M. The short-range order of anodic amorphous oxide films of Ta and Nb. J. Non-Cryst. Solids 1986, 87, 350-360.

Terms in the title (9)： ニオブ ,  酸化物触媒 ,  不飽和脂肪酸 ,  メチルエステル ,  酸化 ,  洞察 ,  触媒 ,  表面反応 ,  研究