Art

J-GLOBAL ID：201902254966242887   Reference number：19A1799173

Enhanced Activity of the Tail-to-tail Dimerization of Michael Acceptors Catalyzed by N-Heterocyclic Carbene and Subsequent Polymer Synthesis from the Resulting Dimers

N-複素環カルベンにより触媒されたMichael受容体の尾から尾への二量化の増強された活性とそれに続く得られた二量体からの重合体合成

Author (4)： Kawai Hiroki (Department of Life Science and Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology) ,  Fukumoto Aoi (Department of Life Science and Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology) ,  Matsuoka Shin-ichi (Department of Life Science and Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology) ,  Suzuki Masato (Department of Life Science and Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology)
Material： Chemistry Letters (Web)
Volume： 48  Issue： 6  Page： 558-561(J-STAGE)  Publication year： 2019 
JST Material Number： U1704A  ISSN： 1348-0715  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *dimerization ,  catalytic activity ,  *polymerization catalyst ,  nitrogen heterocyclic compound ,  *carbene ,  *Michael reaction ,  dimer ,  reaction temperature ,  turnover number ,  ester interchange ,  polycondensation ,  chemical synthesis ,  polyaddition ,  catalytic reaction ,  acceptor ,  Click Chemistry ,  click polymerization ,  organic catalysis ,  electron accepting group ,  unsaturated fatty acid ,  olefin compound ,  carboxylate (ester)
Semi thesaurus term： electroattracting group

Author keywords (3)： Tail-to-tail dimerization ,  N-Heterocyclic carbene ,  Polyester

JST classification (2)： Addition reaction,elimination reaction  (CF02030M) ,  Polymerization catalyst,polymerization initiator  (CG04070V)

Substance index (9)： 1,3,4-Triphenyl-4,5-dihydro-1H-1,2,4-triazole ,  1,3,4-Triphenyl-5-methoxy-4,5-dihydro-1H-1,2,4-triazole ,  Acrylic acid butyl ,  Methacrylic acid allyl ,  Itaconic acid diethyl ,  Methacrylic acid glycidyl ,  N,N-Dimethylacrylamide ,  Methacrylic acid tert-butyl ,  Methacrylic acid butyl

Reference (37)：

• 1) R. Sustmann, H. J. Hornung, T. Schupp, B. Patzke, J. Mol. Catal. 1993, 85, 149.
• 2) B. Patzke, R. Sustmann, J. Organomet. Chem. 1994, 480, 65.
• 3) P. Pertici, V. Ballantini, P. Salvadori, M. A. Bennett, Organometallics 1995, 14, 2565.
• 4) K. Kashiwagi, R. Sugise, T. Shimakawa, T. Matuura, M. Shirai, F. Kakiuchi, S. Murai, Organometallics 1997, 16, 2233.
• 5) A. Fukuoka, T. Nagano, S. Furuta, M. Yoshizawa, M. Hirano, S. Komiya, Bull. Chem. Soc. Jpn. 1998, 71, 1409.

Terms in the title (9)： N-複素環カルベン ,  触媒 ,  受容体 ,  尾 ,  二量化 ,  増強 ,  活性 ,  二量体 ,  重合体合成