Art

J-GLOBAL ID：201902255410968028   Reference number：19A0071054

Asymmetric Michael addition of malonic diesters to acrylates by phase-transfer catalysis toward the construction of quaternary stereogenic α-carbons

第四立体選択性α-炭素の構築に向けた相間移動触媒によるマロン酸エステルのアクリル酸エステルへの不斉Michael付加【JST・京大機械翻訳】

Author (8)： Odanaka Yuki (School of Pharmacy, Showa University, 1-5-8 Hatanodai, Shinagawa-ku, Tokyo, 142-8555, Japan) ,  Kanemitsu Takuya (School of Pharmacy, Showa University, 1-5-8 Hatanodai, Shinagawa-ku, Tokyo, 142-8555, Japan) ,  Iwasaki Kanako (School of Pharmacy, Showa University, 1-5-8 Hatanodai, Shinagawa-ku, Tokyo, 142-8555, Japan) ,  Mochizuki Yukiko (School of Pharmacy, Showa University, 1-5-8 Hatanodai, Shinagawa-ku, Tokyo, 142-8555, Japan) ,  Miyazaki Michiko (School of Pharmacy, Showa University, 1-5-8 Hatanodai, Shinagawa-ku, Tokyo, 142-8555, Japan) ,  Nagata Kazuhiro (School of Pharmacy, Showa University, 1-5-8 Hatanodai, Shinagawa-ku, Tokyo, 142-8555, Japan) ,  Kato Masaru (School of Pharmacy, Showa University, 1-5-8 Hatanodai, Shinagawa-ku, Tokyo, 142-8555, Japan) ,  Itoh Takashi (School of Pharmacy, Showa University, 1-5-8 Hatanodai, Shinagawa-ku, Tokyo, 142-8555, Japan)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 75  Issue： 2  Page： 209-219  Publication year： 2019 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Abstract/Point： A highly enantioselective cons...

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Thesaurus term： Curtius rearrangement ,  *phase transfer catalyst ,  chloride ,  asymmetric synthesis ,  *stereoselectivity ,  *Michael reaction ,  chemical yield ,  enantioselectivity ,  stereocenter ,  all carbon ,  *Acrylates ,  *Malonates
Semi thesaurus term： *マロナート , 【Automatic Indexing@JST】

Author keywords (5)： Asymmetric synthesis ,  Organocatalysis ,  Phase-transfer catalysis ,  Michael addition ,  Quaternary stereocenters

JST classification (3)： Aliphatic carboxylic esters,anhydrides,acid halides,acyl peroxides  (CF03210P) ,  Pyridines  (CF07095Q) ,  Other catalysts  (CB06123Z)

Terms in the title (7)： 立体選択性 ,  炭素 ,  構築 ,  相間移動触媒 ,  マロン酸エステル ,  アクリル酸エステル ,  Michael付加