Art

J-GLOBAL ID：201902263615205062   Reference number：19A2043159

Palladium-Catalyzed Umpolung Type-II Cyclization of Allylic Carbonate-Aldehydes Leading to 3-Methylenecycloalkanol Derivatives

パラジウム触媒によるアリルカーボネート-アルデヒドの極性化第二種環化による3-メチレンシクロアルカノール誘導体の生成【JST・京大機械翻訳】

Author (4)： Tsukamoto Hirokazu (Graduate School of Pharmaceutical Sciences, Tohoku University, 6-3 Aza-aoba, Aramaki, Aoba-ku, Sendai, 980-8578, Japan) ,  Tsukamoto Hirokazu (Department of Pharmaceutical Sciences, Yokohama University of Pharmacy, 601 Matano-cho, Totsuka-ku, Yokohama, 245-0066, Japan) ,  Kawase Ayumu (Graduate School of Pharmaceutical Sciences, Tohoku University, 6-3 Aza-aoba, Aramaki, Aoba-ku, Sendai, 980-8578, Japan) ,  Doi Takayuki (Graduate School of Pharmaceutical Sciences, Tohoku University, 6-3 Aza-aoba, Aramaki, Aoba-ku, Sendai, 980-8578, Japan)
Material： Advanced Synthesis & Catalysis  (Adv Synth Catal)
Volume： 361  Issue： 16  Page： 3733-3738  Publication year： 2019 
JST Material Number： W1343A  ISSN： 1615-4150  CODEN： ASCAF7  Document type： Article
Article type： 原著論文  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Abstract/Point： Palladium-catalyzed umpolung t...

Register(free) or Log In to access     To see more with JDream III (charged).   {{ this.onShowAbsJLink("http://jdream3.com/lp/jglobal/index.html?docNo=19A2043159&from=J-GLOBAL&jstjournalNo=W1343A") }}

Thesaurus term： substrate (biochemistry) ,  Carbonic Acid ,  intermediate ,  *Palladium ,  allylation ,  reducing agent ,  *aldehyde ,  diphosphane ,  Decarboxylation ,  transition state ,  *cyclization reaction ,  *palladium catalyst ,  enantioselectivity ,  chirality ,  aliphatic carboxylic acid

Author keywords (6)： allylic carbonate ,  diastereoselectivity ,  enantioselectivity ,  one-pot ,  palladium ,  umpolung cyclization

JST classification (1)： Aromatic monocyclic aldehydes  (CF05160X)

Substance index (1)： Formic acid

Terms in the title (4)： パラジウム触媒 ,  アルデヒド ,  環化 ,  誘導体