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J-GLOBAL ID：201902271977552459   Reference number：19A1799217

Preparation of Enantioenriched Chiral Organic Molecules by Dynamic Asymmetric Induction from a Outer Chiral Source

外部キラル源からの動的不斉誘導によるエナンチオ濃縮キラル有機分子の調製

Author (12)： Igawa Kazunobu (Institute for Materials Chemistry and Engineering, and IRCCS, Kyushu University) ,  Igawa Kazunobu (Department of Molecular and Material Sciences, Kyushu University) ,  Kawasaki Yuuya (Institute for Materials Chemistry and Engineering, and IRCCS, Kyushu University) ,  Ano Yusuke (Institute for Materials Chemistry and Engineering, and IRCCS, Kyushu University) ,  Kashiwagi Takeru (Institute for Materials Chemistry and Engineering, and IRCCS, Kyushu University) ,  Ogawa Kouhei (Department of Molecular and Material Sciences, Kyushu University) ,  Hayashi Jun-ichi (Department of Molecular and Material Sciences, Kyushu University) ,  Morita Ryota (Department of Molecular and Material Sciences, Kyushu University) ,  Yoshioka Yukari (Department of Molecular and Material Sciences, Kyushu University) ,  Uehara Kazuhiro (Institute for Materials Chemistry and Engineering, and IRCCS, Kyushu University) ,  Tomooka Katsuhiko (Institute for Materials Chemistry and Engineering, and IRCCS, Kyushu University) ,  Tomooka Katsuhiko (Department of Molecular and Material Sciences, Kyushu University)
Material： Chemistry Letters (Web)
Volume： 48  Issue： 7  Page： 726-729(J-STAGE)  Publication year： 2019 
JST Material Number： U1704A  ISSN： 1348-0715  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *asymmetric reaction ,  enantiomer ,  amylose ,  cellulose derivative
Semi thesaurus term： enantiomeric excess ,  *asymmetric induction

Author keywords (3)： Dynamic asymmetric induction ,  Dynamic chiral molecule ,  Static chiral molecule

JST classification (1)： Stereochemistry of organic reaction  (CF02130V)

Substance index (10)： 2-[(9bR)-1-(4-methylbenzenesulfonyl)-2H,4H,5H-benzo[g]indol-9b-yl]ethyl acetate ,  (9bR)-9b-(chloromethyl)-1-(4-methylbenzenesulfonyl)-2H,4H,5H-benzo[g]indole ,  (7aS)-7a-iodo-1-(4-methylbenzenesulfonyl)-4,5-dihydro-2H-indole ,  (1R,13S)-1-(2-アセトキシエチル)-11-トシル-11-アザ-14-オキサトリシクロ[11.1.0.0^4,9]テトラデカン-4(9),5,7-トリエン ,  (1R,13S)-1-(クロロメチル)-11-トシル-11-アザ-14-オキサトリシクロ[11.1.0.0^4,9]テトラデカン-4(9),5,7-トリエン ,  N-[(1S,2S)-2-ethenyl-2-(2-hydroxyethyl)-3,4-dihydro-1H-naphthalen-1-yl]-4-methylbenzenesulfonamide ,  (4R)-5-ethenyl-4-methyl-2-(4-methylbenzenesulfonyl)-1,3,4,5,6,7-hexahydro-2-benzazonine ,  1-Tosyl-2,5,6,9-tetrahydro-1H-azonine ,  N-[(1S,6S)-6-ethenylcyclohex-2-en-1-yl]-4-methylbenzenesulfonamide ,  (1R,9R)-3-トシル-10-オキサ-3-アザビシクロ[7.1.0]デカ-5-エン

Reference (31)：

• 1) a) Asymmetric Synthesis, ed. by J. D. Morrison, Academic Press, New York, 1983-1985, Vol. 1-5.
• 1) b) Comprehensive Chirality, ed. by E. M. Carreira, H. Yamamoto, Elsevier, Amsterdam, 2012, Vol. 1-9.
• 2) E. L. Eliel, S. H. Wilen, Stereochemistry of Organic Compounds, Wiley, New York, 1994.
• 3) C. Wolf, Dynamic Stereochemistry of Chiral Compounds: Principles and Applications, RSC Publishing, Cambridge, 2008.
• 4) a) K. Tomooka, M. Suzuki, M. Shimada, S. Yanagitsuru, K. Uehara, Org. Lett. 2006, 8, 963.

Terms in the title (5)： キラル ,  不斉誘導 ,  濃縮 ,  有機分子 ,  調製