Art

J-GLOBAL ID：201902274753529851   Reference number：19A1998173

Enhanced Aggregation of Stimuli Responsive Surfactants by Esterolytic Reactions

エステル分解反応による刺激応答性界面活性剤の凝集増強

Author (5)： Asakawa Tsuyoshi (School of Chemistry, College of Science and Engineering, Kanazawa University) ,  Fujii Akina (School of Chemistry, College of Science and Engineering, Kanazawa University) ,  Yoneda Nodoka (School of Chemistry, College of Science and Engineering, Kanazawa University) ,  Ohta Akio (School of Chemistry, College of Science and Engineering, Kanazawa University) ,  Asakawa Hitoshi (School of Chemistry, College of Science and Engineering, Kanazawa University)
Material： Journal of Oleo Science  (J Oleo Sci)
Volume： 68  Issue： 6  Page： 573-580(J-STAGE)  Publication year： 2019 
JST Material Number： G0238A  ISSN： 1345-8957  CODEN： JOSOAP  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *surfactant ,  ester interchange ,  Dynamic Light Scattering ,  air oxidation ,  Hydrogen Peroxide ,  critical micelle concentration ,  disulfide bond ,  *thioester ,  micelle formation ,  alkyl group ,  aggregation ,  gemini surfactant ,  concentration (ratio) ,  aliphatic alcohol ,  thiol ,  diol ,  secondary alcohol
Semi thesaurus term： interesterification

Author keywords (4)： thiol-thioester exchange ,  esterolytic reaction ,  enhanced aggregation ,  stimuli responsive surfactant

JST classification (1)： Other cleaning agents  (YG02040W)

Substance index (2)： Dithiothreitol ,  4-Nitrophenyl hexanoate

Reference (19)：

• 1) Rowan, S.J.; Cantrill, S.J.; Cousins, G.R.L.; Sanders, J.K.M.; Stoddart, J.F. Dynamic covalent chemistry. Angew. Chem. Int. Ed. 41, 898-952 (2002).
• 2) Johnson, E.C.B.; Kent, Stephen B.H. Insights into the mechanism and catalysis of the native chemical ligation reaction. J. Am. Chem. Soc. 128, 6640-6646 (2006).
• 3) Enrique A. Castro; Kinetics and mechanisms of reactions of thiol, thiono, and dithio analogues of carboxylic esters with nucleophiles. Chem. Rev. 99, 3505-3524 (1999).
• 4) Dong, J.; Xun, Z.; Zeng, Y.; Yu, T.; Han, Y.; Chen, J.; Li, Y.Y.; Yang, G.; Li, Y. Theoretical study on the alkaline hydrolysis of methyl thioacetate in aqueous solution. J. Phys. Chem. A 115, 13523-13533 (2011).
• 5) Bracher, P.J.; Snyder, P.W.; Bohall, B.R.; Whitesides, G.M. The relative rates of thiol-thioester exchange and hydrolysis for alkyl and aryl thioalkanoates in water. Orig. Life Evol. Biosph. 4, 399-412 (2011).

Terms in the title (6)： エステル ,  分解反応 ,  刺激応答性 ,  界面活性剤 ,  凝集 ,  増強