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J-GLOBAL ID：201902279503757500   Reference number：19A0968431

Stepwise Introduction of Different Substituents to α-Chloro-ω-hydrooligosilanes: Convenient Synthesis of Unsymmetrically Substituted Oligosilanes

α-クロロ-ω-ヒドロオリゴシランへの異なる置換基の段階的導入 非対称置換オリゴシランの便利な合成【JST・京大機械翻訳】

Author (6)： Kanno Ken-ichiro (Division of Molecular Science, Graduate School of Science and Technology, Gunma University, Kiryu, Gunma 376-8515, Japan) ,  Aikawa Yumi (Division of Molecular Science, Graduate School of Science and Technology, Gunma University, Kiryu, Gunma 376-8515, Japan) ,  Niwayama Yuka (Division of Molecular Science, Graduate School of Science and Technology, Gunma University, Kiryu, Gunma 376-8515, Japan) ,  Ino Misaki (Division of Molecular Science, Graduate School of Science and Technology, Gunma University, Kiryu, Gunma 376-8515, Japan) ,  Kawamura Kento (Division of Molecular Science, Graduate School of Science and Technology, Gunma University, Kiryu, Gunma 376-8515, Japan) ,  Kyushin Soichiro (Division of Molecular Science, Graduate School of Science and Technology, Gunma University, Kiryu, Gunma 376-8515, Japan)
Material： Inorganics (Web)
Volume： 6  Issue： 3  Page： 99  Publication year： 2018 
JST Material Number： U7205A  ISSN： 2304-6740  Document type： Article
Article type： 原著論文  Country of issue： Switzerland (CHE)  Language： ENGLISH (EN)

Abstract/Point： A series of unsymmetrically su...

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Thesaurus term： ruthenium catalyst ,  alcohol ,  aryl group ,  alkoxylation ,  Grignard reagent ,  Ruthenium ,  dehydrogenation ,  *asymmetry ,  *substituent

Author keywords (4)： α-chloro-ω-hydrooligosilane ,  titanium ,  ruthenium ,  dehydrogenative alkoxylation

JST classification (1)： Organosilicon compounds  (CF08030C)

Reference (47)：

• Miller, R.D.; Michl, J. Polysilane high polymers. Chem. Rev. 1989, 89, 1359-1410.
• Beckmann, J. Oligosilanes. In Comprehensive Organometallic Chemistry III; Crabtree, R.H., Mingos, D.M.P., Eds.; Elsevier: Oxford, UK, 2007; Volume 3, pp. 409-512.
• Marschner, C. Oligosilanes. In Functional Molecular Silicon Compounds I: Regular Oxidation States; Scheschkewitz, D., Ed.; Springer: Cham, Switzerland, 2014; pp. 163-228.
• Mignani, G.; Krämer, A.; Puccetti, G.; Ledoux, I.; Soula, G.; Zyss, J.; Meyrueix, R. A new class of silicon compounds with interesting nonlinear optical effects. Organometallics 1990, 9, 2640-2643.
• Mignani, G.; Krämer, A.; Puccetti, G.; Ledoux, I.; Zyss, J.; Soula, G. Effect of a weak donor on the intramolecular charge transfer of molecules containing two neighboring silicon atoms. Organometallics 1991, 10, 3656-3659.

Terms in the title (4)： 置換基 ,  段階 ,  非対称 ,  置換