Art

J-GLOBAL ID：201902285689595622   Reference number：19A0953907

Amino Amide Organocatalysts for Asymmetric Michael Addition of β-Keto Esters with β-Nitroolefins

β-ニトロオレフィンとβ-ケトエステルの不斉Michael付加のためのアミノアミド有機触媒

Author (9)： Owolabi Isiaka Alade (Division of Sustainable and Environmental Engineering, Graduate School of Engineering, Muroran Institute of Technology) ,  Chennapuram Madhu (Division of Sustainable and Environmental Engineering, Graduate School of Engineering, Muroran Institute of Technology) ,  Seki Chigusa (Division of Sustainable and Environmental Engineering, Graduate School of Engineering, Muroran Institute of Technology) ,  Okuyama Yuko (Tohoku Medical and Pharmaceutical University) ,  Kwon Eunsang (Research and Analytical Center for Giant Molecules, Graduate School of Sciences, Tohoku University) ,  Uwai Koji (Division of Sustainable and Environmental Engineering, Graduate School of Engineering, Muroran Institute of Technology) ,  Tokiwa Michio (Tokiwakai Group) ,  Takeshita Mitsuhiro (Tokiwakai Group) ,  Nakano Hiroto (Division of Sustainable and Environmental Engineering, Graduate School of Engineering, Muroran Institute of Technology)
Material： Bulletin of the Chemical Society of Japan (Web)
Volume： 92  Issue： 3  Page： 696-701(J-STAGE)  Publication year： 2019 
JST Material Number： U1703A  ISSN： 1348-0634  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *keto ester ,  *olefin compound ,  *aliphatic nitro compound ,  *Michael reaction ,  carboxamide ,  amino group ,  asymmetric synthesis ,  catalytic reaction ,  catalyst preparation ,  stereoselectivity ,  stereoselective reaction ,  aromatic compound ,  base catalytic reaction ,  diastereomer ,  optical isomerism ,  functional group protection ,  deprotection
Semi thesaurus term： *Michael addition reaction ,  diastereofacial selectivity ,  Styrenes ,  organocatalysis

Author keywords (3)： Amino amide ,  Organocatalyst ,  Michael addition

JST classification (4)： Preparation of catalysts  (CB06110P) ,  Catalytic reactions(homogeneous system)  (CB06090Q) ,  Addition reaction,elimination reaction  (CF02030M) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (22)： (E)-β-Nitrostyrene ,  Methy 2-oxocyclopentanecarboxylate ,  (S)-N-(1-ピレニル)-2-アミノ-3,3-ジメチルブタンアミド ,  (S)-N-(4-ピレニル)-2-アミノ-3,3-ジメチルブタンアミド ,  (S)-N-(1-ピレニル)-2-アミノ-2-フェニルアセトアミド ,  (S)-N-(1-ピレニル)-2-アミノ-3-フェニルプロパンアミド ,  (S)-N-(1-Anthryl)-2-amino-3,3-dimethylbutanamide ,  (S)-N-(1-ナフチル)-2-アミノ-3,3-ジメチルブタンアミド ,  N-(1-Naphthyl)-L-valinamide ,  (S)-N-(1-ナフチル)-2-アミノ-2-フェニルアセトアミド ,  N-(1-Naphthyl)-L-phenylalaninamide ,  1-[(S)-1-Phenyl-2-nitroethyl]-2-oxocyclopentane-1α-carboxylic acid methyl ester ,  1-[(S)-1-(4-Methylphenyl)-2-nitroethyl]-2-oxocyclopentane-1α-carboxylic acid methyl ester ,  1-[(S)-1-(2-Methylphenyl)-2-nitroethyl]-2-oxocyclopentane-1α-carboxylic acid methyl ester ,  1-[(S)-1-(4-Methoxyphenyl)-2-nitroethyl]-2-oxocyclopentane-1α-carboxylic acid methyl ester ,  1-[(S)-1-(4-Chlorophenyl)-2-nitroethyl]-2-oxocyclopentane-1α-carboxylic acid methyl ester ,  1-[(S)-1-(4-Fluorophenyl)-2-nitroethyl]-2-oxocyclopentane-1α-carboxylic acid methyl ester ,  (R)-1-[(S)-1-(2-フリル)-2-ニトロエチル]-2-オキソシクロペンタン-1-カルボン酸メチル ,  1-[(S)-1-(2-Thienyl)-2-nitroethyl]-2-oxocyclopentane-1α-carboxylic acid methyl ester ,  1-Oxo-2-[(S)-1-phenyl-2-nitroethyl]indan-2β-carboxylic acid methyl ester ,  (R)-1-[(S)-1-フェニル-2-ニトロエチル]-2-オキソシクロヘキサン-1-カルボン酸メチル ,  (R)-1-[(S)-1-フェニル-2-ニトロエチル]-2-オキソシクロヘプタン-1-カルボン酸メチル

Reference (95)：

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Terms in the title (4)： オレフィン ,  ケトエステル ,  Michael付加 ,  有機触媒