Art

J-GLOBAL ID：201902286217770618   Reference number：19A0953889

Development of Asymmetric Reactions Catalyzed by Ruthenium Complexes with Two Kinds of Ligands

2種類の配位子を有するルテニウム錯体触媒による不斉反応の開発

Author (3)： Ohkuma Takeshi (Division of Applied Chemistry & Frontier Chemistry Center, Faculty of Engineering, Hokkaido University) ,  Kurono Nobuhito (Department of Chemistry, Hamamatsu University School of Medicine) ,  Arai Noriyoshi (Division of Applied Chemistry & Frontier Chemistry Center, Faculty of Engineering, Hokkaido University)
Material： Bulletin of the Chemical Society of Japan (Web)
Volume： 92  Issue： 3  Page： 475-504(J-STAGE)  Publication year： 2019 
JST Material Number： U1703A  ISSN： 1348-0634  Document type： Article
Article type： 解説  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *ruthenium complex ,  ruthenium catalyst ,  *asymmetric synthesis ,  *asymmetric catalyst ,  *chiral ligand ,  ligand ,  ligand effect ,  nucleophilic addition reaction ,  condensation reaction ,  asymmetric reduction ,  stereoselectivity ,  enantiomer ,  cyanation ,  silylation ,  phosphine complex ,  imine ,  unsaturated ketone ,  catalytic reaction ,  catalytic activity ,  catalyst preparation ,  optical activity ,  optical isomerism ,  ammine complex ,  chloro complex ,  aldimine ,  enantioselectivity ,  cyanosilylation ,  Strecker reaction ,  aromatic ketone
Semi thesaurus term： Strecker synthesis

Author keywords (3)： Asymmetric reactions ,  Molecular catalysis ,  Ruthenium complexes

JST classification (5)： Stereochemistry of organic reaction  (CF02130V) ,  Platinum family element complexes  (CE01100E) ,  Preparation of catalysts  (CB06110P) ,  Catalytic reactions in general  (CB06080F) ,  Oxidation,reduction  (CF02060T)

Substance index (28)： (R)-1-(1-Naphthyl)ethanol ,  (R)-1-Phenylethanol ,  (S)-BINAP ,  1-Acetylnaphthalene ,  2-(Aminomethyl)pyridine ,  Acetophenone ,  2,2′-Bis[bis(3,5-xylyl)phosphino]-1,1′-binaphthalene ,  (2S)-1,1-Di(4-methoxyphenyl)-2-isopropylethylenediamine ,  Segphos ,  4,4′-Bi[5-[bis(3,5-xylyl)phosphino]-1,3-benzodioxole] ,  p-Tol-BINAP ,  (2S,4S)-2,4-Bis[bis(3,5-dimethylphenyl)phosphino]pentane ,  BINAP ,  (2R)-N,N-Dimethyl-2-phenylethylenediamine ,  (2R)-N,N-Dibutyl-2-phenylethylenediamine ,  (1S)-1-Phenyl-2-(dimethylamino)ethaneamine ,  (-)-Stilbenediamine ,  Phenylglycine ,  4-Methoxy-L-phenylglycine ,  L-tert-Leucine ,  dpbp ,  (1R)-1-(2-Thienyl)ethanol ,  (S)-2-Methoxybenzhydrol ,  (2R)-4-Phenyl-3-buten-2-ol ,  1,1′-(2,6-Pyridinediyl)bis[(R)-ethanol] ,  (R)-1-Cyclopropylethanol ,  (R)-1,1-Dimethoxy-2-propanol ,  N-メチル-N-[(S)-2-フェニル-2-ヒドロキシエチル]ベンズアミド

Reference (150)：

• 1) See for example: a) Science of Synthesis: Stereoselective Synthesis, ed. by J. G. de Vries, G. A. Molander, P. A. Evans, Thieme, Stuttgart, 2010, Vols. 1-3.
• 1) b) Comprehensive Chirality, ed. by E. M. Carreira, H. Yamamoto, Elsevier, Amsterdam, 2012, Vols. 1-9.
• 2) Reviews: a) T. Ohkuma, Proc. Jpn. Acad., Ser. B 2010, 86, 202.
• 2) b) T. Ohkuma, N. Arai, Chem. Rec. 2016, 16, 2801.
• 3) Review: T. Ohkuma, N. Kurono, Synlett 2012, 23, 1865.

Terms in the title (5)： 配位子 ,  ルテニウム ,  錯体触媒 ,  不斉反応 ,  開発