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J-GLOBAL ID：201902291965995562   Reference number：19A2742524

Peroxycarbenium Ions as the “Gatekeepers” in Reaction Design: Assistance from Inverse Alpha-Effect in Three-Component β-Alkoxy-β-peroxylactones Synthesis

反応設計における「ゲートキーパー」としてのペルオキシカルベニウムイオン 三成分β-アルコキシ-β-ペルオキシラクトン合成における逆アルファ効果からの支援【JST・京大機械翻訳】

Author (10)： Vil' Vera A. (N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospect, Moscow, 119991, Russian Federation) ,  Vil' Vera A. (All-Russian Research Institute for Phytopathology, B. Vyazyomy, Moscow Region, 143050, Russian Federation) ,  Barsegyan Yana A. (N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospect, Moscow, 119991, Russian Federation) ,  Barsegyan Yana A. (All-Russian Research Institute for Phytopathology, B. Vyazyomy, Moscow Region, 143050, Russian Federation) ,  Barsukov Denis V. (N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospect, Moscow, 119991, Russian Federation) ,  Korlyukov Alexander A. (A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Street, Moscow, 119991, Russian Federation) ,  Korlyukov Alexander A. (Pirogov Russian National Research Medical University, Moscow, 117997, Russian Federation) ,  Alabugin Igor V. (Department of Chemistry and Biochemistry, Florida State University, Tallahassee, 32309, USA) ,  Terent'ev Alexander O. (N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospect, Moscow, 119991, Russian Federation) ,  Terent'ev Alexander O. (All-Russian Research Institute for Phytopathology, B. Vyazyomy, Moscow Region, 143050, Russian Federation)
Material： Chemistry - European Journal  (Chem Eur J)
Volume： 25  Issue： 63  Page： 14460-14468  Publication year： 2019 
JST Material Number： W0744A  ISSN： 0947-6539  CODEN： CEUJED  Document type： Article
Article type： 原著論文  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Abstract/Point： Stereoelectronic interactions ...

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Thesaurus term： chemical synthesis ,  cyclization reaction ,  carbonyl group ,  interaction ,  *alcohol ,  oxidation ,  reactivity ,  instability ,  intermediate ,  peroxidation ,  thermodynamics ,  peroxide(inorganic) ,  condensation reaction ,  peroxide(organic)
Semi thesaurus term： 環状 ,  有機過酸化物 , 【Automatic Indexing@JST】

Author keywords (5)： anomeric effects ,  carbonyl compounds ,  peroxides ,  peroxycarbenium ion ,  stereoelectronic effects

JST classification (4)： Other catalysts  (CB06123Z) ,  Aliphatic ethers  (CF03100V) ,  Aliphatic aldehydes  (CF03180F) ,  Alkenes  (CF03030T)

Terms in the title (2)： 反応設計 ,  支援