Art

J-GLOBAL ID：202002215439212231   Reference number：20A0391075

Efficient Generation and Synthetic Applications of Alkyl-Substituted Siloxycarbenes: Suppression of Norrish-Type Fragmentations of Alkanoylsilanes by Triplet Energy Transfer

アルキル置換シロキシカルベンの効率的な生成と合成への応用 三重項エネルギー移動によるアルカノイルシランのNorrish型フラグメンテーションの抑制【JST・京大機械翻訳】

Author (5)： Ishida Kento (Department of Chemistry, Faculty of Science, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo, 171-8588, Japan) ,  Yamazaki Hokuto (Department of Chemistry, Faculty of Science, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo, 171-8588, Japan) ,  Hagiwara Chihiro (Department of Chemistry, Faculty of Science, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo, 171-8588, Japan) ,  Abe Manabu (Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, Hiroshima, 739-8526, Japan) ,  Kusama Hiroyuki (Department of Chemistry, Faculty of Science, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo, 171-8588, Japan)
Material： Chemistry - European Journal  (Chem Eur J)
Volume： 26  Issue： 6  Page： 1249-1253  Publication year： 2020 
JST Material Number： W0744A  ISSN： 0947-6539  CODEN： CEUJED  Document type： Article
Article type： 原著論文  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Abstract/Point： Acylsilanes have been known to...

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Thesaurus term： isomerization ,  *energy transfer ,  complex(compound) ,  photoirradiation ,  *carbene ,  sensitizer ,  precursor(substance) ,  coupling reaction ,  aldehyde ,  *fragmentation ,  photochemistry ,  visible light
Semi thesaurus term： ボロン酸エステル , 【Automatic Indexing@JST】

Author keywords (5)： acylsilanes ,  energy transfer ,  photochemistry ,  siloxycarbenes ,  triplet sensitizer

JST classification (5)： Platinum family element complexes  (CE01100E) ,  Electronic structure of molecules  (BH05010Q) ,  6A and 7A groups  (CE01080F) ,  Imidazoles  (CF07083X) ,  Structure effect on organic reaction  (CF02110Z)

Terms in the title (5)： 置換 ,  応用 ,  三重項 ,  エネルギー移動 ,  フラグメンテーション