Art

J-GLOBAL ID：202002232766587048   Reference number：20A2522136

A meta-Selective C-H Alumination of Mono-Substituted Benzene by Using An Alkyl-Substituted Al Anion through Hydride-Eliminating S_NAr Reaction

ヒドリド脱離S_NAr反応を経るアルキル置換Alアニオンを用いたモノ置換ベンゼンのメタ選択的C-Hアルミニウム化【JST・京大機械翻訳】

Author (4)： Kurumada Satoshi (Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi, 464-8603, Japan) ,  Sugita Kengo (Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi, 464-8603, Japan) ,  Nakano Ryo (Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi, 464-8603, Japan) ,  Yamashita Makoto (Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi, 464-8603, Japan)
Material： Angewandte Chemie. International Edition  (Angewandte Chemie. International Edition in English)
Volume： 59  Issue： 46  Page： 20381-20384  Publication year： 2020 
JST Material Number： H0127B  ISSN： 1433-7851  CODEN： ACIEAY  Document type： Article
Article type： 原著論文  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Abstract/Point： Reaction of an Al-centered ani...

Register(free) or Log In to access     To see more with JDream III (charged).   {{ this.onShowAbsJLink("http://jdream3.com/lp/jglobal/index.html?docNo=20A2522136&from=J-GLOBAL&jstjournalNo=H0127B") }}

Thesaurus term： *desorption ,  *aluminum ,  substituent effect ,  *hydride ,  reaction mechanism ,  *anion ,  density functional method ,  alkylbenzene
Semi thesaurus term： 電子制御 ,  芳香族置換 ,  速度論的同位体効果 ,  密度汎関数計算 , 【Automatic Indexing@JST】

Author keywords (5)： aluminum anions ,  density functional calculations ,  kinetic isotope effect ,  nucleophilic aromatic substitution ,  substituent effect

JST classification (3)： Proteins and peptides in general  (EB03010N) ,  Electrochemical reaction  (CB07050F) ,  Aromatic monocyclic amine,imine,quaternary ammonium,immonium compounds  (CF05050D)

Substance index (1)： Toluene

Terms in the title (7)： ヒドリド ,  脱離 ,  置換 ,  Al ,  アニオン ,  置換ベンゼン ,  アルミニウム