Art

J-GLOBAL ID：202002238305967164   Reference number：20A0843973

Kinetic Analysis of Enantioselective Hydrogenation of 2,3-(E)-Diarylpropenoic Acids over a Chiral Cinchona Alkaloid-Modified Pd/C Catalyst

キラルなCinchonaアルカロイド修飾Pd/C触媒上での2,3-(E)-ジアリールプロペン酸のエナンチオ選択的水素化の速度論的解析

Author (7)： Kim Bokeun (Graduate School of Material Science, University of Hyogo) ,  Nakatsuji Makoto (Graduate School of Material Science, University of Hyogo) ,  Mameda Takuya (Graduate School of Material Science, University of Hyogo) ,  Kubota Takeshi (Department of Material Science, Shimane University) ,  Fujita Morifumi (Graduate School of Material Science, University of Hyogo) ,  Sugimura Takashi (Graduate School of Material Science, University of Hyogo) ,  Okamoto Yasuaki (Graduate School of Material Science, University of Hyogo)
Material： Bulletin of the Chemical Society of Japan (Web)
Volume： 93  Issue： 1  Page： 163-175(J-STAGE)  Publication year： 2020 
JST Material Number： U1703A  ISSN： 1348-0634  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *quinoline alkaloid ,  *palladium catalyst ,  activated carbon ,  hydrogenation ,  *enantiomer ,  reaction kinetics ,  *asymmetric reduction ,  optical isomerism ,  unsaturated carboxylic acid ,  aliphatic carboxylic acid ,  nitrogen heterocyclic compound ,  polynuclear aromatic compound ,  olefin compound ,  aromatic compound ,  catalytic reaction ,  heterogeneous reaction ,  molecular recognition ,  parameter ,  catalytic reduction ,  supported catalyst ,  stereoselectivity ,  stereochemistry ,  stereoselective reaction ,  optical resolution ,  bridged compound ,  vinyl compound ,  phenol ether ,  secondary alcohol ,  alcohol
Semi thesaurus term： *Cinchona Alkaloids ,  Pd/C ,  enantiomeric excess ,  enantioselective hydrogenation ,  quinoline derivative ,  Stilbenes ,  chemical kinetics ,  kinetic resolution ,  Reaction Parameters ,  heterogeneous catalysis

Author keywords (3)： Kinetic analysis ,  Enantioselective hydrogenation ,  Cinchona-modified Pd

JST classification (7)： Nobel metal catalysts  (CB06122I) ,  Quinolines,isoquinolines  (CF07096H) ,  Oxidation,reduction  (CF02060T) ,  Reaction kinetics and catalyst in general  (CB06010G) ,  Preparation of catalysts  (CB06110P) ,  Alkaloids  (CF10030D) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (13)： (2R)-2,3-Bis(4-methoxyphenyl)propionic acid ,  (2S)-3-(4-Fluorophenyl)-2-(2-methoxyphenyl)propanoic acid ,  (E)-3-(4-Fluorophenyl)-2-(2-methoxyphenyl)acrylic acid ,  (2R)-2,3-Diphenylpropanoic acid ,  (R)-2-(2-メトキシフェニル)-3-(4-フルオロフェニル)プロパン酸 ,  (S)-2,3-Bis(4-methoxyphenyl)propanoic acid ,  (S)-α-Phenylhydrocinnamic acid ,  (E)-2,3-Bis(4-methoxyphenyl)acrylic acid ,  α-Phenylcinnamic acid ,  Quinine ,  Quinidine ,  Cinchonidine ,  Cinchonine

Reference (95)：

• 1) R. Noyori, Asymmetric Catalysis in Organic Synthesis, Wiley & Sons, New York, <b>1994</b>.
• 2) S. Akabori, Y. Izumi, Y. Fujii, S. Sakurai, Nature 1956, 178, 323.
• 3) a) Y. Izumi, Adv. Catal. 1983, 32, 215.
• 3) b) T. Sugimura, Catal. Surv. Asia 1999, 3, 37.
• 3) c) T. Osawa, T. Harada, O. Takayasu, Top. Catal. 2000, 13, 155.

Terms in the title (9)： キラル ,  Cinchonaアルカロイド ,  修飾 ,  Pd ,  触媒 ,  酸 ,  エナンチオ選択的水素化 ,  速度論 ,  解析