Art

J-GLOBAL ID：202002248623185397   Reference number：20A2453357

N-H insertion reaction via an iron carbenoid from α-diazophenylpropionate and its application to the formal total synthesis of stizolobinic acid

α-ジアゾフェニルプロピオナートからの鉄カルベノイドを経由するN-H挿入反応およびスチゾロビン酸の形式的全合成への応用【JST・京大機械翻訳】

Author (7)： Shinohara Hideyuki (School of Pharmacy, Nihon University, 7-7-1, Narashinodai, Funabashi, Chiba, 274-8555, Japan) ,  Shinohara Hideyuki (Yamagata Prefectural Institute of Public Health, 1-6-6 Tohkamachi, Yamagata-shi, Yamagata, 990-0031, Japan) ,  Saito Hiroaki (School of Pharmacy, Nihon University, 7-7-1, Narashinodai, Funabashi, Chiba, 274-8555, Japan) ,  Homma Hiroki (Yamagata Prefectural Institute of Public Health, 1-6-6 Tohkamachi, Yamagata-shi, Yamagata, 990-0031, Japan) ,  Mizuta Katsumi (Yamagata Prefectural Institute of Public Health, 1-6-6 Tohkamachi, Yamagata-shi, Yamagata, 990-0031, Japan) ,  Miyairi Shinichi (School of Pharmacy, Nihon University, 7-7-1, Narashinodai, Funabashi, Chiba, 274-8555, Japan) ,  Uchiyama Taketo (School of Pharmacy, Nihon University, 7-7-1, Narashinodai, Funabashi, Chiba, 274-8555, Japan)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 76  Issue： 46  Page： Null  Publication year： 2020 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Abstract/Point： The formal total synthesis of ...

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Thesaurus term： *Iron ,  chloride ,  aliphatic amine ,  *insertion reaction ,  Proteins ,  *total synthesis ,  porphyrin complex ,  *carbenoid ,  iron(III)

Author keywords (5)： N-H insertion ,  Iron carbenoid ,  Aliphatic amine ,  Stizolobinic acid ,  Mushroom toxin

JST classification (5)： Catalytic reactions in general  (CB06080F) ,  Nobel metal catalysts  (CB06122I) ,  Cyclization reaction,ring-opening reaction  (CF02050I) ,  Stereochemistry of organic reaction  (CF02130V) ,  Aliphatic hydroxylamines,hydrazines and other polynitrogen compounds  (CF03080W)

Substance index (1)： Tetrakis(pentafluorophenyl)porphyrin

Terms in the title (6)： 鉄 ,  カルベノイド ,  挿入反応 ,  酸 ,  全合成 ,  応用