Art

J-GLOBAL ID：202002262672477035   Reference number：20A1720132

Cu(II) Porphyrin-catalyzed Coupling of Alkyl Tosylates and Grignard Reagents

アルキルトシラートとGrignard試薬のCu(II)ポルフィリン触媒カップリング

Author (3)： Matsuoka Iori (Department of Material Chemistry, Graduate School of Engineering, Kyoto University) ,  Kurahashi Takuya (Department of Material Chemistry, Graduate School of Engineering, Kyoto University) ,  Matsubara Seijiro (Department of Material Chemistry, Graduate School of Engineering, Kyoto University)
Material： Chemistry Letters (Web)
Volume： 49  Issue： 5  Page： 442-445(J-STAGE)  Publication year： 2020 
JST Material Number： U1704A  ISSN： 1348-0715  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： copper complex ,  porphyrin complex ,  *copper catalyst ,  Grignard reagent ,  ESR ,  XAFS ,  reaction mechanism ,  nucleophilic addition reaction ,  electron transfer ,  *coupling reaction ,  spin density ,  density functional method ,  *catalytic reaction

Author keywords (3)： Cross-coupling reaction ,  Electron-transfer ,  In-situ XAFS

JST classification (2)： Other catalysts  (CB06123Z) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (9)： 1-Phenyl-3-cyclohexylbutane ,  (R)-1-トシル-3-シクロヘキシルピロリジン ,  1-フェニル-3,4,4-トリメチルペンタン ,  N-(4,4-dimethylpentyl)-4-methylbenzenesulfonamide ,  (3R)-1-(4-methylbenzenesulfonyl)pyrrolidin-3-yl 4-methylbenzenesulfonate ,  p-Toluenesulfonic acid (4-phenylbutane-2-yl) ester ,  3-(4-methylbenzenesulfonamido)propyl 4-methylbenzenesulfonate ,  Cyclohexylmagnesium bromide ,  tert-Butylmagnesium bromide

Reference (38)：

• 1) a) Metal-Catalyzed Cross-Coupling Reactions, 2nd ed., ed. by A. de Meijere, F. Diederich, Wiley-VCH, Weinheim, 2004.
• 1) b) Metal-catalyzed Cross-Coupling Reactions, 1st ed., ed. by F. Diederich, P. J. Stang, Wiley-VCH, Weinheim, 1998.
• 1) For selected reviews on metal-catalyzed cross-coupling reactions, see: c) R. Jana, T. P. Pathak, M. S. Sigman, Chem. Rev. 2011, 111, 1417.
• 1) d) W.-T. T. Chang, R. C. Smith, C. S. Regens, A. D. Bailey, N. S. Werner, S. E. Denmark, Org. React. 2011, 75, 213.
• 1) e) Y. Nakao, T. Hiyama, Chem. Soc. Rev. 2011, 40, 4893.

Terms in the title (5)： Grignard試薬 ,  Cu ,  ポルフィリン ,  触媒 ,  カップリング