Art

J-GLOBAL ID：202002266481287545   Reference number：20A0370913

SUGAR BASED γ-AMINO ALCOHOL ORGANOCATALYST FOR ASYMMETRIC MICHAEL ADDITION OF β-KETO ESTERS WITH NITROOLEFINS

β-ケトエステルのニトロオレフィンによる不斉Michael付加のための糖をベースとするγ-アミノアルコール有機触媒

Author (11)： GANESAN Divakar (Muroran Inst. Technol., Muroran) ,  CHENNAPURAM Madhu (Muroran Inst. Technol., Muroran) ,  BEGUM Zubeda (Muroran Inst. Technol., Muroran) ,  SEKI Chigusa (Muroran Inst. Technol., Muroran) ,  OKUYAMA Yuko (Tohoku Medical and Pharmaceutical Univ., Sendai, JPN) ,  KWON Eunsang (Tohoku Univ., Sendai, JPN) ,  UWAI Koji (Muroran Inst. Technol., Muroran) ,  TOKIWA Michio (Tokiwakai Group, Iwaki, JPN) ,  TOKIWA Suguru (Tokiwakai Group, Iwaki, JPN) ,  TAKESHITA Mitsuhiro (Tokiwakai Group, Iwaki, JPN) ,  NAKANO Hiroto (Muroran Inst. Technol., Muroran)
Material： Heterocycles  (International Journal for Reviews and Communications in Heterocyclic Chemistry)
Volume： 98  Issue： 11  Page： 1536-1545  Publication year： Nov. 01, 2019 
JST Material Number： S0966A  ISSN： 0385-5414  CODEN： HTCYAM  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,  catalytic reaction ,  catalytic activity ,  aminoalcohol ,  *keto ester ,  *aliphatic nitro compound ,  *olefin compound ,  alicyclic ketone ,  spiro-compound ,  *Michael reaction ,  reaction mechanism
Semi thesaurus term： organocatalyst

JST classification (2)： Aliphatic nitro and nitroso compounds  (CF03060A) ,  Catalytic reactions in general  (CB06080F)

Substance index (16)： (R)-1-[(S)-1-Phenyl-2-nitroethyl]-2-oxocyclopentanecarboxylic acid ethyl ester ,  1-[(S)-1-Phenyl-2-nitroethyl]-2-oxocyclopentane-1α-carboxylic acid methyl ester ,  1-[(S)-1-(4-Chlorophenyl)-2-nitroethyl]-2-oxocyclopentane-1α-carboxylic acid methyl ester ,  1-[(S)-1-(4-Methylphenyl)-2-nitroethyl]-2-oxocyclopentane-1α-carboxylic acid methyl ester ,  (R)-1-[(S)-1-(2-フリル)-2-ニトロエチル]-2-オキソシクロペンタン-1-カルボン酸メチル ,  (R)-1-[(S)-1-フェニル-2-ニトロエチル]-2-オキソシクロヘキサン-1-カルボン酸メチル ,  (R)-1-[(S)-1-フェニル-2-ニトロエチル]-2-オキソシクロヘプタン-1-カルボン酸メチル ,  1-Oxo-2-[(S)-1-phenyl-2-nitroethyl]indan-2β-carboxylic acid methyl ester ,  1-[(S)-1-(2-Thienyl)-2-nitroethyl]-2-oxocyclopentane-1α-carboxylic acid methyl ester ,  1-[(S)-1-(3-Methoxyphenyl)-2-nitroethyl]-2-oxocyclopentane-1α-carboxylic acid methyl ester ,  1-[(S)-1-(4-Fluorophenyl)-2-nitroethyl]-2-oxocyclopentane-1α-carboxylic acid methyl ester ,  1-O,2-O-Isopropylidene-5-(tert-butylamino)-5-deoxy-α-D-xylofuranose ,  Methy 2-oxocyclopentanecarboxylate ,  β-Nitrostyrene ,  メチル(1R)-1-[(1S)-1-(ナフタレン-1-イル)-2-ニトロエチル]-2-オキソシクロペンタン-1-カルボキシラート ,  メチル(1R)-1-[(1S)-2-ニトロ-1-(4-ニトロフェニル)エチル]-2-オキソシクロペンタン-1-カルボキシラート

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Terms in the title (6)： ケトエステル ,  オレフィン ,  Michael付加 ,  糖 ,  アミノアルコール ,  有機触媒