Art

J-GLOBAL ID：202002269875672406   Reference number：20A0323188

Enantioselective Stereodivergent Approach to α-Hydroxy Skipped Dienes: Synthesis of the Western Polyene Fragment of Corallopyronin A

α-ヒドロキシスキップジエンへのエナンチオ選択的立体分岐アプローチ:コラロピロニンAのウエスタンポリエンフラグメントの合成

Author (4)： Nagashima Yoshiyuki (Department of Applied Chemistry, Faculty of Science and Technology, Keio University) ,  Okada Yuto (Department of Applied Chemistry, Faculty of Science and Technology, Keio University) ,  Sato Takaaki (Department of Applied Chemistry, Faculty of Science and Technology, Keio University) ,  Chida Noritaka (Department of Applied Chemistry, Faculty of Science and Technology, Keio University)
Material： Chemistry Letters (Web)
Volume： 48  Issue： 12  Page： 1519-1521(J-STAGE)  Publication year： 2019 
JST Material Number： U1704A  ISSN： 1348-0715  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *stereoselective reaction ,  stereoisomer ,  coupling reaction ,  hydroboration ,  *chemical synthesis ,  *diene ,  natural product synthesis
Semi thesaurus term： substructure

Author keywords (3)： Allene ,  Hydroboration ,  Skipped diene

JST classification (2)： Stereochemistry of organic reaction  (CF02130V) ,  Alkenes  (CF03030T)

Substance index (3)： (2E,4E,8R)-8-(tert-Butyldimethylsiloxy)-2,5,9-trimethyl-2,4,9,10-undecatetraenoic acid ethyl ester ,  (2E,4E,8R,9E)-2,5,9-トリメチル-8-(tert-ブチルジメチルシリルオキシ)-11-ヒドロキシ-2,4,9-ウンデカトリエン酸エチル ,  Corallopyronin A

Reference (82)：

• 1) For recent selected examples on stereoselective and convergent methods for skipped dienes, see; a) K. Kaneda, T. Uchiyama, Y. Fujiwara, T. Imanaka, S. Teranishi, J. Org. Chem. 1979, 44, 55.
• 1) b) B. M. Trost, A. Indolese, J. Am. Chem. Soc. 1993, 115, 4361.
• 1) c) B. M. Trost, A. F. Indolese, T. J. J. Muller, B. Treptow, J. Am. Chem. Soc. 1995, 117, 615.
• 1) d) A. N. Thadani, V. H. Rawal, Org. Lett. 2002, 4, 4317.
• 1) e) A. N. Thadani, V. H. Rawal, Org. Lett. 2002, 4, 4321.

Terms in the title (2)： 立体 ,  分岐