Art

J-GLOBAL ID：202002279291491161   Reference number：20A0323190

Reactions of 1-Alkynes with a Molybdenum-Silyl Complex: Stable σ-Acetylide Complexes Containing a Pentadentate Ligand Comprised of a P₂SiP₂ Framework

1-アルキン類とモリブデン-シリル錯体との反応:P₂SiP₂骨格からなる五座配位子を含む安定なσ-アセチリド錯体

Author (3)： Minato Makoto (Department of Materials Chemistry, Faculty of Engineering, Yokohama National University) ,  Watanabe Kyosuke (Department of Materials Chemistry, Faculty of Engineering, Yokohama National University) ,  Maeda Kengo (Department of Materials Chemistry, Faculty of Engineering, Yokohama National University)
Material： Chemistry Letters (Web)
Volume： 48  Issue： 12  Page： 1526-1528(J-STAGE)  Publication year： 2019 
JST Material Number： U1704A  ISSN： 1348-0715  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *molybdenum complex ,  hydrido complex ,  *organosilicon compound ,  reaction mechanism ,  molecular structure ,  *alkyne complex ,  aromatic hydrocarbon ,  acetylenic compound ,  fatty acid ,  drug

Author keywords (3)： Molybdenum ,  Trans influence ,  σ-Acetylide

JST classification (2)： 6A and 7A groups  (CE01080F) ,  Alkynes  (CF03040E)

Substance index (4)： 3,3-Dimethyl-1-butyne ,  Bis[2-[phenyl[2-(diphenylphosphino)ethyl]phosphino]phenyl]phenylsilane ,  Phenylacetylene ,  Acetic acid

Reference (27)：

• 1) For leading references see: a) G. Jia, D. W. Meek, Organometallics 1991, 10, 1444.
• 1) b) A. M. Echavarren, J. Lopez, A. Santos, A. Romero, J. A. Hermoso, A. Vegas, Organometallics 1991, 10, 2371.
• 1) c) H.-H. Chou, Y.-C. Lin, S.-L. Huang, Y.-H. Liu, Y. Wang, Organometallics 2008, 27, 5212.
• 1) d) B. Chatterjee, C. Gunanathan, Chem. Commun. 2016, 52, 4509.
• 2) A. Hills, D. L. Hughes, N. Kashef, M. A. N. D. A. Lemos, A. J. L. Pombeiro, R. L. Richards, J. Chem. Soc., Dalton Trans. 1992, 1775.

Terms in the title (5)： モリブデン ,  シリル錯体 ,  骨格 ,  配位子 ,  アセチリド錯体