Art

J-GLOBAL ID：202002286683274691   Reference number：20A0539977

LIGAND ASSESSMENT FOR THE SUZUKI-MIYAURA CROSS COUPLING REACTION OF ARYL AND HETEROARYL BROMIDES WITH n-BUTYLBORONIC ACID. THE ADVANTAGES OF BUCHWALD’S S-PHOS

アリールおよびヘテロアリールブロミドとn-ブチルボロン酸とのSuzuki-Miyaura交差カップリング反応の配位子評価:Buchwaldのホスフィン配位子の利点

Author (9)： JAGUSCH Thomas (Queen’s Univ., ON, CAN) ,  NERDINGER Sven (Archimica GmbH, Frankfurt am Main, DEU) ,  LEHNEMANN Bernd (Archimica GmbH, Frankfurt am Main, DEU) ,  SCHERER Stefan (Archimica GmbH, Frankfurt am Main, DEU) ,  MEUDT Andreas (Archimica GmbH, Frankfurt am Main, DEU) ,  SNIECKUS Victor (Queen’s Univ., ON, CAN) ,  NEUNER Sandro (Univ. Innsbruck, Fac. of Chemistry and Pharmacy, Innsbruck, AUT) ,  NEUNER Sandro (Univ. for Health Sci., Medical Informatics and Technol., Hall in Tirol) ,  SCHOTTENBERGER Herwig (Univ. Innsbruck, Fac. of Chemistry and Pharmacy, Innsbruck, AUT)
Material： Heterocycles  (International Journal for Reviews and Communications in Heterocyclic Chemistry)
Volume： 101  Issue： 2  Page： 631-644  Publication year： Jan. 01, 2020 
JST Material Number： S0966A  ISSN： 0385-5414  CODEN： HTCYAM  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *Suzuki reaction ,  organic boron acid ,  aromatic bromine compound ,  palladium catalyst ,  *palladium complex ,  *ligand effect ,  *phosphine complex ,  phosphine ,  catalyst preparation ,  catalytic reaction ,  heterogeneous reaction ,  cross coupling reaction ,  alkylation
Semi thesaurus term： *Suzuki-Miyaura cross-coupling reaction

JST classification (5)： Organoboron compounds  (CF08020R) ,  Addition reaction,elimination reaction  (CF02030M) ,  Preparation of catalysts  (CB06110P) ,  Catalytic reactions(heterogeneous system)  (CB06100E) ,  Platinum family element complexes  (CE01100E)

Substance index (14)： 2-Dicyclohexylphosphino-2′,6′-dimethoxybiphenyl ,  2′-(Dicyclohexylphosphino)biphenyl-2-ol ,  2-(Dicyclohexylphosphino)-2′-methoxybiphenyl ,  2-Butylaniline ,  2-Butylthiophene ,  2-Bromoaniline ,  2-Bromothiophene ,  3-Butylpyridine ,  3-Bromopyridine ,  Phosphorous acid triisopropyl ,  Butylboronic acid ,  Butylbenzene ,  Propylmagnesium bromide ,  Bromobenzene

Reference (32)：

• D. L. Sandrock, Alkylboron Cross-Coupling Reactions, In Science of Synthesis: Cross Coupling and Heck-type Reactions, ed. by G. A. Molander, Vol. 1, Georg Thieme Verlag, Stuttgart, 2013, p 323.
• (a) J. C.-H. Lee and D. G. Hall, Metal-Catalyzed Cross-Coupling Reactions and More, ed. by A. de Meijere, S. Braese, and M. Oestreich, Vol. 3, Wiley-VCH, Weinheim, 2014, p 65; (b) C. C. C. Johansson Seechurn, M. O. Kitching, T. J. Colacot, and V. Snieckus, Angew. Chem. Int. Ed., 2012, 51, 5062; (c) I. Maluenda and O. Navarrao, Molecules, 2015, 20, 7528; (d) A. J. J. Lennox and G. C. Lloyd-Jones, Chem. Soc. Rev., 2014, 43, 412.
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• (a) S. R. Chemler, D. Trauner, and S. J. Danishefsky, Angew. Chem. Int. Ed., 2001, 40, 4544; (b) H. Doucet, Eur. J. Org. Chem., 2008, 2013; (c) R. Jana, T. P. Pathak, and M. Sigman, Chem. Rev., 2011, 111, 1417; (d) G. Seidel and A. Fürstner, Chem. Commun., 2012, 48, 2055.

Terms in the title (7)： N-ブチル ,  ボロン酸 ,  Suzuki-Miyaura交差カップリング反応 ,  配位子 ,  評価 ,  ホスフィン配位子 ,  利点