Art
J-GLOBAL ID：202102229790776998   Reference number：21A0239530

Enantioselective Protonation: Hydrophosphinylation of 1,1-Vinyl Azaheterocycle N-Oxides Catalyzed by Chiral Bis(guanidino)iminophosphorane Organosuperbase

エナンチオ選択的プロトン化 キラルなビス(グアニジノ)イミノホスホラン有機超塩基を触媒とする1,1-ビニルアザ複素環N-オキシド類のヒドロホスフィニル化【JST・京大機械翻訳】
Author (4)：
Das Saikat

About Das Saikat

(Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai, 980-8578, Japan)

About Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai, 980-8578, Japan

, 
Hu Qiupeng

About Hu Qiupeng

(Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai, 980-8578, Japan)

About Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai, 980-8578, Japan

, 
Kondoh Azusa

About Kondoh Azusa

(Research and Analytical Center for Giant Molecules, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai, 980-8578, Japan)

About Research and Analytical Center for Giant Molecules, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai, 980-8578, Japan

, 
Terada Masahiro

About Terada Masahiro

(Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai, 980-8578, Japan)

About Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai, 980-8578, Japan


Material：
Angewandte Chemie. International Edition  (Angewandte Chemie. International Edition in English)

About Angewandte Chemie. International Edition


Volume： 60  Issue： 3  Page： 1417-1422  Publication year： 2021 
JST Material Number： H0127B  ISSN： 1433-7851  CODEN： ACIEAY  Document type： Article
Article type： 原著論文  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)
Abstract/Point：
Abstract/Point
Japanese summary of the article(about several hundred characters).
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Enantioselective protonation b...
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Thesaurus term：
Thesaurus term/Semi thesaurus term
Keywords indexed to the article.
All keywords is available on JDreamIII(charged).
On J-GLOBAL, this item will be available after more than half a year after the record posted. In addtion, medical articles require to login to MyJ-GLOBAL.
*protonation

About protonation

, 
metal complex

About metal complex

, 
conjugation

About conjugation

, 
phosphine oxide

About phosphine oxide

, 
reaction system

About reaction system

, 
acidity(property)

About acidity(property)

, 
nucleophilic reagent

About nucleophilic reagent

, 
chiral ligand

About chiral ligand


Semi thesaurus term：
Thesaurus term/Semi thesaurus term
Keywords indexed to the article.
All keywords is available on JDreamIII(charged).
On J-GLOBAL, this item will be available after more than half a year after the record posted. In addtion, medical articles require to login to MyJ-GLOBAL.
キラリティ

About キラリティ

, 
*超塩基

About 超塩基

, 
*アミンオキシド

About アミンオキシド

, 
有機触媒

About 有機触媒

, 
塩基触媒

About 塩基触媒

, 
エナンチオマ純度

About エナンチオマ純度

, 【Automatic Indexing@JST】
Author keywords (5)：
base catalysis

About base catalysis

, 
chiral ligands

About chiral ligands

, 
enantioselective protonation

About enantioselective protonation

, 
hydrophosphinylation

About hydrophosphinylation

, 
organocatalysis

About organocatalysis

JST classification (2)：
JST classification
Category name(code) classified by JST.
Addition reaction,elimination reaction 
(CF02030M)

About Addition reaction,elimination reaction

,  Organop phosphorus compounds 
(CF08040N)

About Organop phosphorus compounds

Terms in the title (7)：
Terms in the title
Keywords automatically extracted from the title.
プロトン化

About プロトン化

, 
キラル

About キラル

, 
ビス

About ビス

, 
超塩基

About 超塩基

, 
触媒

About 触媒

, 
複素環

About 複素環

, 
N-オキシド

About N-オキシド


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