Art

J-GLOBAL ID：202102236530273013   Reference number：21A0433010

Chemoselective Cleavage of Si-C(sp³) Bonds in Unactivated Tetraalkylsilanes Using Iodine Tris(trifluoroacetate)

ヨウ素トリス(トリフルオロアセタートを用いた非活性化テトラアルキルシランにおけるSi-C(sp=η3)結合の化学選択的開裂【JST・京大機械翻訳】

Author (14)： Matsuoka Keitaro (Faculty of Pharmaceutical Sciences, Hokkaido University, Japan) ,  Komami Narumi (Faculty of Pharmaceutical Sciences, Hokkaido University, Japan) ,  Kojima Masahiro (Faculty of Pharmaceutical Sciences, Hokkaido University, Japan) ,  Mita Tsuyoshi (Institute for Chemical Reaction Design and Discovery (WPI-ICReDD), Hokkaido University, Japan) ,  Mita Tsuyoshi (JST, ERATO Maeda Artificial Intelligence for Chemical Reaction Design and Discovery Project, Hokkaido, Japan) ,  Suzuki Kimichi (Institute for Chemical Reaction Design and Discovery (WPI-ICReDD), Hokkaido University, Japan) ,  Suzuki Kimichi (JST, ERATO Maeda Artificial Intelligence for Chemical Reaction Design and Discovery Project, Hokkaido, Japan) ,  Suzuki Kimichi (Department of Chemistry, Faculty of Science, Hokkaido University, Japan) ,  Maeda Satoshi (Institute for Chemical Reaction Design and Discovery (WPI-ICReDD), Hokkaido University, Japan) ,  Maeda Satoshi (JST, ERATO Maeda Artificial Intelligence for Chemical Reaction Design and Discovery Project, Hokkaido, Japan) ,  Maeda Satoshi (Department of Chemistry, Faculty of Science, Hokkaido University, Japan) ,  Yoshino Tatsuhiko (Faculty of Pharmaceutical Sciences, Hokkaido University, Japan) ,  Matsunaga Shigeki (Faculty of Pharmaceutical Sciences, Hokkaido University, Japan) ,  Matsunaga Shigeki (Global Station for Biosurfaces and Drug Discovery, Hokkaido University, Japan)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 143  Issue： 1  Page： 103-108  Publication year： 2021 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Abstract/Point： Organosilanes are syntheticall...

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Thesaurus term： NMR ,  polarity ,  oxidation ,  *silicon ,  alcohol ,  organic chemistry ,  alkyl group ,  precursor(substance) ,  inactivation
Semi thesaurus term： 官能基 ,  反応条件 ,  有機合成 ,  有機シラン ,  Si-O結合 ,  密度汎関数計算 , 【Automatic Indexing@JST】

JST classification (1)： Organosilicon compounds  (CF08030C)

Terms in the title (6)： ヨウ素 ,  トリフルオロアセタート ,  非活性化 ,  Si ,  化学 ,  開裂