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J-GLOBAL ID：200902106138767447   Reference number：00A1013087

Cycloaddition of New N-Unsubstituted Azomethine Ylides Generated from N-(Trimethylsilylmethyl)thioureas to Electron-Deficient Olefins, Acetylenes and Aldehydes, Synthetic Equivalents of Nonstabilized Aminonitrile Ylides.

N-(トリメチルシリルメチル)チオ尿素類から発生させた新規なN-非置換アゾメチンイリドの電子不足オレフィン,アセチレン類及びアルデヒドへの環状付加,非安定化アミノニトリルイリドの合成的等価体

Author (6)： TSUGE O (Sojo Univ., Kumamoto, JPN) ,  HATTA T (Sojo Univ., Kumamoto, JPN) ,  TASHIRO H (Sojo Univ., Kumamoto, JPN) ,  KAKURA Y (Sojo Univ., Kumamoto, JPN) ,  MAEDA H (Sojo Univ., Kumamoto, JPN) ,  KAKEHI A (Shinshu Univ., Nagano, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 56  Issue： 39  Page： 7723-7735  Publication year： Sep. 22, 2000 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *cycloaddition ,...
Semi thesaurus term： 非安定化アミノニトリルイリド

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JST classification (2)： Aliphatic ureas,carbamic acids,guanidines  (CF03240W) ,  Cyclization reaction,ring-opening reaction  (CF02050I)

Substance index (71)： Fumaric acid dimethyl ,  Fumaronitrile ,  Benzaldehyde ,  (Trimethylsilyl)methyl isothiocyanate ,  N-Phenyl-N′-(trimethylsilylmethyl)-S-methylisothiourea ,  [(Trimethylsilyl)methyl][(methylthio)pyrrolizinomethylene]amine ,  [(Trimethylsilyl)methyl][(methylthio)piperidinomethylene]amine ,  [(Trimethylsilyl)methyl][(methylthio)morpholinomethylene]amine ,  N-Methylmaleimide ,  N-Phenylmaleinimide ,  N-Phenyl-2-methylmaleimide ,  2-Methyl-4-anilino-6,6a-dihydropyrrolo[3,4-c]pyrrole-1,3(2H,3aH)-dione ,  2-Methyl-4-pyrrolizino-6,6a-dihydropyrrolo[3,4-c]pyrrole-1,3(2H,3aH)-dione ,  2-Methyl-4-piperidino-6,6a-dihydropyrrolo[3,4-c]pyrrole-1,3(2H,3aH)-dione ,  2-Methyl-4-morpholino-6,6a-dihydropyrrolo[3,4-c]pyrrole-1,3(2H,3aH)-dione ,  1-Methyl-3-(methylthio)pyrrolidine-2,5-dione ,  2-Methyl-6-anilino-6a-(1-methyl-2,5-dioxo-3-pyrrolidinyl)-4,6a-dihydropyrrolo[3,4-c]pyrrole-1,3(2H,3aH)-dione ,  2-Methyl-3a-(1-methyl-2,5-dioxo-3-pyrrolidinyl)-4-pyrrolizino-6,6a-dihydropyrrolo[3,4-c]pyrrole-1,3(2H,3aH)-dione ,  2-Methyl-3a-(1-methyl-2,5-dioxo-3-pyrrolidinyl)-4-morpholino-6,6a-dihydropyrrolo[3,4-c]pyrrole-1,3(2H,3aH)-dione ,  2-Phenyl-4-anilino-6,6a-dihydropyrrolo[3,4-c]pyrrole-1,3(2H,3aH)-dione ,  2-Phenyl-4-morpholino-6,6a-dihydropyrrolo[3,4-c]pyrrole-1,3(2H,3aH)-dione ,  1-Phenyl-3-(methylthio)pyrrolidine-2,5-dione ,  2-Phenyl-6-morpholino-6a-(1-phenyl-2,5-dioxo-3-pyrrolidinyl)-4,6a-dihydropyrrolo[3,4-c]pyrrole-1,3(2H,3aH)-dione ,  2-Phenyl-3a-methyl-6-anilino-4,6a-dihydropyrrolo[3,4-c]pyrrole-1,3(2H,3aH)-dione ,  2-Phenyl-3a-methyl-6-pyrrolizino-4,6a-dihydropyrrolo[3,4-c]pyrrole-1,3(2H,3aH)-dione ,  2-Phenyl-3a-methyl-6-piperidino-4,6a-dihydropyrrolo[3,4-c]pyrrole-1,3(2H,3aH)-dione ,  2-Phenyl-3a-methyl-6-morpholino-4,6a-dihydropyrrolo[3,4-c]pyrrole-1,3(2H,3aH)-dione ,  2-Phenyl-6-anilino-6a-methyl-4,6a-dihydropyrrolo[3,4-c]pyrrole-1,3(2H,3aH)-dione ,  2-Phenyl-6-pyrrolizino-6a-methyl-4,6a-dihydropyrrolo[3,4-c]pyrrole-1,3(2H,3aH)-dione ,  2-Phenyl-6-piperidino-6a-methyl-4,6a-dihydropyrrolo[3,4-c]pyrrole-1,3(2H,3aH)-dione ,  2-Phenyl-6-morpholino-6a-methyl-4,6a-dihydropyrrolo[3,4-c]pyrrole-1,3(2H,3aH)-dione ,  1-Phenyl-3-(methylthio)-3-methylpyrrolidine-2,5-dione ,  Maleic acid dimethyl ,  2-Chloroacrylonitrile ,  (4R)-4-Hydroxy-5-anilino-3,4-dihydro-2H-pyrrole-3,4-dicarboxylic acid dimethyl ester ,  (4R)-5-Anilino-3,4-dihydro-2H-pyrrole-3,4-dicarboxylic acid dimethyl ester ,  (4R)-5-Pyrrolizino-3,4-dihydro-2H-pyrrole-3,4-dicarboxylic acid dimethyl ester ,  (4R)-5-Piperidino-3,4-dihydro-2H-pyrrole-3,4-dicarboxylic acid dimethyl ester ,  (4R)-5-Morpholino-3,4-dihydro-2H-pyrrole-3,4-dicarboxylic acid dimethyl ester ,  2-(Phenylamino)-2-pyrroline-3,4-dicarbonitrile ,  2-Pyrrolizino-2-pyrroline-3,4-dicarbonitrile ,  2-Piperidino-2-pyrroline-3,4-dicarbonitrile ,  2-Morpholino-2-pyrroline-3,4-dicarbonitrile ,  2-Anilino-1H-pyrrole-3-carbonitrile ,  2-Piperidino-1H-pyrrole-3-carbonitrile ,  2-Morpholino-1H-pyrrole-3-carbonitrile ,  2-(Phenylamino)-3-chloro-1-pyrroline-3-carbonitrile ,  2-Butynedioic acid dimethyl ,  2-Anilino-1H-pyrrole-3,4-dicarboxylic acid dimethyl ester ,  2-[2-Pyrrolizino-3,4-bis(methoxycarbonyl)-1-pyrrolyl]maleic acid dimethyl ester ,  2-[2-Pyrrolizino-3,4-bis(methoxycarbonyl)-1-pyrrolyl]fumaric acid dimethyl ester ,  2-Piperidino-1H-pyrrole-3,4-dicarboxylic acid dimethyl ester ,  2-[2-Piperidino-3,4-bis(methoxycarbonyl)-1-pyrrolyl]maleic acid dimethyl ester ,  2-[2-Piperidino-3,4-bis(methoxycarbonyl)-1-pyrrolyl]fumaric acid dimethyl ester ,  2-Morpholino-1H-pyrrole-3,4-dicarboxylic acid dimethyl ester ,  2-[2-Morpholino-3,4-bis(methoxycarbonyl)-1-pyrrolyl]maleic acid dimethyl ester ,  2-[2-Morpholino-3,4-bis(methoxycarbonyl)-1-pyrrolyl]fumaric acid dimethyl ester ,  4-Chlorobenzaldehyde ,  4-Nitrobenzaldehyde ,  Pyridine-2-carbaldehyde ,  Pyridine-3-carbaldehyde ,  4-Pyridinecarbaldehyde ,  2-Anilino-5-phenyl-2-oxazoline ,  2-Anilino-5-(4-chlorophenyl)-2-oxazoline ,  2-Anilino-5-(4-nitrophenyl)-2-oxazoline ,  2-Piperidino-5-(4-nitrophenyl)-2-oxazoline ,  2-Morpholino-5-(4-nitrophenyl)-2-oxazoline ,  2-Anilino-5-(2-pyridyl)-2-oxazoline ,  2-Anilino-5-(3-pyridyl)-2-oxazoline ,  2-Anilino-5-(4-pyridyl)-2-oxazoline ,  1-Phenyl-2,3-dimethylisothiourea

Terms in the title (10)： チオ尿素 ,  非置換 ,  アゾメチンイリド ,  電子 ,  オレフィン ,  アセチレン類 ,  アルデヒド ,  環状付加 ,  安定化 ,  等価