Art

J-GLOBAL ID：200902112056494698   Reference number：97A0231599

Regioselective Reductive Opening of 4,6-O-Benzylidene Acetals of glucose or glucosamine Derivatives by BH₃ Me₂NH-BF₃ OEt₂.

BH₃・Me₂NH-BF₃・OEt₂によるグルコース又はグルコサミン誘導体の4,6-O-ベンジリデンアセタールの位置選択的還元的開環

Author (6)： OIKAWA M (Osaka Univ., Osaka, JPN) ,  LIU W-C (Osaka Univ., Osaka, JPN) ,  NAKAI Y (Osaka Univ., Osaka, JPN) ,  KOSHIDA S (Osaka Univ., Osaka, JPN) ,  FUKASE K (Osaka Univ., Osaka, JPN) ,  KUSUMOTO S (Osaka Univ., Osaka, JPN)
Material： Synlett
Issue： 12  Page： 1179-1180  Publication year： Dec. 1996 
JST Material Number： W0113A  ISSN： 0936-5214  CODEN： SYNLES  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： reduction (reaction) ,...
Semi thesaurus term： glucose ,...

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JST classification (2)： Monosaccharides  (CF10052H) ,  Cyclization reaction,ring-opening reaction  (CF02050I)

Substance index (16)： Allyl 2-O,3-O-diacetyl-4-O,6-O-benzylidene-α-D-glucopyranoside ,  Allyl 2-[[(2,2,2-trichloroethoxy)carbonyl]amino]-3-O-[(2,2,2-trichloroethoxy)carbonyl]-4-O,6-O-benzylidene-2-deoxy-α-D-glucopyranoside ,  Allyl 2-[[(2,2,2-trichloroethoxy)carbonyl]amino]-3-[(R)-3-(benzyloxy)tetradecanoyl]-4-O,6-O-benzylidene-2,3-dideoxy-α-D-glucopyranoside ,  Methyl 2-O,3-O-dibenzyl-4-O,6-O-benzylidene-α-D-glucopyranoside ,  Methyl 2-[(benzyloxycarbonyl)amino]-3-O-benzyl-4-O,6-O-benzylidene-2-deoxy-α-D-glucopyranoside ,  N-(2,2,2-Trichloroethoxycarbonyl)-1-O-allyl-4-O,6-O-benzylidene-α-D-glucosamine ,  Allyl 2-O,3-O-diacetyl-6-O-benzyl-α-D-glucopyranoside ,  Allyl 2-[[(2,2,2-trichloroethoxy)carbonyl]amino]-3-O-[(2,2,2-trichloroethoxy)carbonyl]-6-O-benzyl-2-deoxy-α-D-glucopyranoside ,  Allyl 2-[[(2,2,2-trichloroethoxy)carbonyl]amino]-3-[(R)-3-(benzyloxy)tetradecanoyl]-6-O-benzyl-2,3-dideoxy-α-D-glucopyranoside ,  2-O,3-O,6-O-Tribenzyl-methyl α-D-glucopyranoside ,  1-O-Methyl-N-(benzyloxycarbonyl)-3-O,6-O-dibenzyl-α-D-glucosamine ,  Allyl 2-[[(2,2,2-trichloroethoxy)carbonyl]amino]-6-O-benzyl-2-deoxy-α-D-glucopyranoside ,  Allyl 2-O,3-O-diacetyl-4-O-benzyl-α-D-glucopyranoside ,  2-O,3-O,4-O-Tribenzylmethyl α-D-glucopyranoside ,  Methyl 2-[(benzyloxycarbonyl)amino]-3-O,4-O-dibenzyl-2-deoxy-α-D-glucopyranoside ,  Allyl 2-[[(2,2,2-trichloroethoxy)carbonyl]amino]-4-O-benzyl-2-deoxy-α-D-glucopyranoside

Terms in the title (7)： BH3 ,  BF3 ,  グルコース ,  グルコサミン ,  誘導体 ,  選択的還元 ,  開環