Art

J-GLOBAL ID：200902117018916971   Reference number：00A0845785

π-Facial selectivity in Diels-Alder reactions of cyclopentadienes having π-systems at 5-positions and the solvent effect.

5-位置にπ-系をもつシクロペンタジエン類のDiels-Alder反応におけるπ-面選択性及び溶媒効果

Author (4)： ISHIDA M (Gifu Univ., Gifu, JPN) ,  KOBAYASHI H (Gifu Univ., Gifu, JPN) ,  TOMOHIRO S (Gifu Univ., Gifu, JPN) ,  INAGAKI S (Gifu Univ., Gifu, JPN)
Material： Journal of the Chemical Society. Perkin Transactions. 2  (Perkin Transactions 2)
Issue： 7  Page： 1625-1630  Publication year： Jul. 2000 
JST Material Number： A0640B  ISSN： 1472-779X  CODEN： JCPKBH  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： orbital energy ,...
Semi thesaurus term： orbital hybridization

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JST classification (3)： Cyclopentanes  (CF04040L) ,  Stereochemistry of organic reaction  (CF02130V) ,  Electronic structure of molecules  (BH05010Q)

Substance index (29)： Carbon Tetrachloride ,  Toluene ,  Pyridine ,  Tetrahydrofuran ,  Methanol ,  Ethanol ,  Triethylamine ,  Hempa ,  Acetic acid ,  5-Cyano-1,3-cyclopentadiene ,  1,2,3,4,5-Pentamethyl-2,4-cyclopentadiene-1-carbonitrile ,  2,4-Cyclopentene-1-carboxylic acid ,  1,2,3,4,5-Pentamethyl-2,4-cyclopentadiene-1-carboxylic acid ,  2,4-Cyclopentadiene-1-carboxylic acid ethyl ester ,  1,2,3,4,5-Pentamethyl-2,4-cyclopentadiene-1-carboxylic acid ethyl ester ,  2,4-Cyclopentene-1-carbaldehyde ,  1,2,3,4,5-Pentamethyl-2,4-cyclopentadiene-1-carbaldehyde ,  2,4-Cyclopentadiene-1-carbaldehydeoxime ,  1,2,3,4,5-Pentamethyl-2,4-cyclopentadiene-1-carbaldehyde oxime ,  1-Vinyl-2,4-cyclopentadiene ,  1,2,3,4,5-Pentamethyl-5-vinyl-1,3-cyclopentadiene ,  N-Phenylmaleinimide ,  (7-anti)-N-Phenyl-1α,4α,5,6,7-pentamethyl-7-formylbicyclo[2.2.1]hepta-5-ene-2α,3α-dicarbimide ,  (7-syn)-N-Phenyl-1α,4α,5,6,7-pentamethyl-7-(hydroxyiminomethyl)bicyclo[2.2.1]hepta-5-ene-2α,3α-dicarbimide ,  (7-anti)-N-Phenyl-1α,4α,5,6,7-pentamethyl-7-(hydroxyiminomethyl)bicyclo[2.2.1]hepta-5-ene-2α,3α-dicarbimide ,  (7-syn)-N-Phenyl-1α,4α,5,6,7-pentamethyl-7-vinylbicyclo[2.2.1]hepta-5-ene-2α,3α-dicarbimide ,  (7-anti)-N-Phenyl-1α,4α,5,6,7-pentamethyl-7-vinylbicyclo[2.2.1]hepta-5-ene-2α,3α-dicarbimide ,  2,2,2-Trifluoroethanol ,  N,N,N',N'-Tetramethylethylenediamine

Terms in the title (4)： シクロペンタジエン類 ,  Diels-Alder反応 ,  面選択性 ,  溶媒効果