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J-GLOBAL ID：200902120904091321   Reference number：02A0667729

Inorganic Chemistry Based on Tp Ligands. From Dioxygen Complexes to Organometallic Systems.

Tp配位子に基づく無機化学 二酸素錯体から有機金属系まで

Author (2)： AKITA M (Tokyo Inst. Technol., Yokohama) ,  HIKICHI S (Tokyo Inst. Technol., Yokohama)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 75  Issue： 8  Page： 1657-1679  Publication year： Aug. 15, 2002 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 文献レビュー  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *boron compound ,...

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JST classification (5)： Organoboron compounds  (CF08020R) ,  Transition metal complexes in general  (CE01040N) ,  Crystal structure of complex of transition metals(excluding iron group)  (BK09030X) ,  Electronic structure of molecules  (BH05010Q) ,  Oxidation,reduction  (CF02060T)

Substance index (2)： Tris(3,4,5-trimethyl-1H-pyrazole-1-yl) boronanion ,  Tris[4-methyl-3,5-di(²H₃)methyl-1H-pyrazole-1-yl] boronanion

Reference (188)：

• 1) a) S. Trofimenko, J. Am. Chem. Soc., 88, 1842 (1966).
•  b) S. Trofimenko, Inorg. Synth., 12, 99 (1970).
• 2) Abbreviations used in this paper: Tp^R: hydrotris(pyrazolyl)borato ligands; Tp^{<i>i</i>Pr<FONT SIZE=-2>2</FONT>}: 3,5-diisopropylpyrazolyl derivative; Tp^{Me<FONT SIZE=-2>2</FONT>}: 3,5-dimethylpyrazolyl derivative; Tp^{Me<FONT SIZE=-2>3<FONT/>}: 3,4,5-trimethylpyrazolyl derivative; Tp^{Me<FONT SIZE=-2>2</FONT>,Br}: 3,5-dimethyl-4-bromopyrazolyl derivative; Tp^{Me<FONT SIZE=-2>2</FONT>,X}: 3,5-trimethyl-4-X-pyrazolyl derivative (X: Me, H, Br); Tp^H: the non-substituted parent ligand; pz^R: pyrazolyl group in Tp^R. For compounds, <b>1</b>–<b>3</b>, <b>10</b>, <b>12</b>, <b>31</b>–<b>34</b>, <b>43</b>, <b>44</b> and <b>46</b>, compound numbers without the name of the central metal atom refer to the series of metal complexes of a certain structure and each metal derivative is specified by the superscript. For example, <b>2a</b> stands for the series of (Tp^{<i>i</i>Pr<FONT SIZE=-2>2</FONT>}M)₂(<i>μ</i>-OH)₂-type complexes of various metals, whereas <b>2a</b>^<b>Ni</b> stands for the nickel derivative, (Tp^{<i>i</i>Pr<FONT SIZE=-2>2</FONT>}Ni)₂(<i>μ</i>-OH)₂.
• 3) a) S. Trofimenko, “Scorpionates - The Coordination Chemistry of Polypyrazolylborate Ligands,” Imperial College Press, London (1999).
•  b) S. Trofimenko, Chem. Rev., 93, 943 (1993).

Terms in the title (5)： TP ,  配位子 ,  無機化学 ,  二酸素錯体 ,  有機金属