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J-GLOBAL ID：200902127196608763   Reference number：01A0856027

Stereoselective Synthesis of Chiral 2,3-cis-2-Ethynylaziridines by Base-Mediated Intramolecular Amination of Bromoallenes.

ブロモアレン類の塩基媒介分子内アミノ化によるキラルな2,3-cis-2-エチニルアジリジン類の立体選択的合成

Author (3)： OHNO H (Osaka Univ., Osaka, JPN) ,  HAMAGUCHI H (Osaka Univ., Osaka, JPN) ,  TANAKA T (Osaka Univ., Osaka, JPN)
Material： Organic Letters  (Org Lett)
Volume： 3  Issue： 15  Page： 2269-2271  Publication year： Jul. 26, 2001 
JST Material Number： W1171A  ISSN： 1523-7060  CODEN： ORLEF7  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...

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JST classification (2)： Three-membered heterocyclic compounds  (CF07050R) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (12)： N-[(1S)-1-Isopropyl-4-bromo-2,3-butadienyl]carbamic acid tert-butyl ester ,  N-[(1S)-1-Isopropyl-4-bromo-2,3-butadienyl]-2,4,6-trimethylbenzenesulfonamide ,  N-[(1S)-1-Benzyl-4-bromo-2,3-butadienyl]-p-toluenesulfonamide ,  N-[(1S)-1-[(tert-Butyldimethylsilyloxy)methyl]-4-bromo-2,3-butadienyl]-2,4,6-trimethylbenzenesulfonamide ,  rel-2β^*-Isopropyl-3β^*-ethynylaziridine-1-carboxylic acid tert-butyl ester ,  rel-1-(2,4,6-Trimethylphenylsulfonyl)-2β^*-isopropyl-3β^*-ethynylaziridine ,  rel-1-Tosyl-2β^*-benzyl-3β^*-ethynylaziridine ,  rel-1-(2,4,6-Trimethylphenylsulfonyl)-2β^*-[(tert-butyldimethylsilyloxy)methyl]-3β^*-ethynylaziridine ,  rel-2β^*-Isopropyl-3α^*-ethynylaziridine-1-carboxylic acid tert-butyl ester ,  rel-1-(2,4,6-Trimethylphenylsulfonyl)-2β^*-isopropyl-3α^*-ethynylaziridine ,  rel-1-Tosyl-2β^*-benzyl-3α^*-ethynylaziridine ,  rel-1-(2,4,6-Trimethylphenylsulfonyl)-2β^*-[(tert-butyldimethylsilyloxy)methyl]-3α^*-ethynylaziridine

Terms in the title (5)： 塩基 ,  アミノ化 ,  キラル ,  CIS ,  立体選択的合成