Art

J-GLOBAL ID：200902131893296165   Reference number：03A0015983

Enantioselective preparation of 3,4,5-trisubstituted 4,5-dihydroisoxazoles and their stereoselective elaboration of 5-side chain.

3,4,5-三置換4,5-ジヒドロイソオキサゾールのエナンチオ選択的合成及びそれらの5-側鎖の立体選択的労作

Author (7)： KAMIMURA A (Yamaguchi Univ., Ube, JPN) ,  KANEKO Y (Yamaguchi Univ., Ube, JPN) ,  OHTA A (Yamaguchi Univ., Ube, JPN) ,  MATSUURA K (Yamaguchi Univ., Ube, JPN) ,  FUJIMOTO Y (Yamaguchi Univ., Ube, JPN) ,  KAKEHI A (Shinshu Univ., Nagano, JPN) ,  KANEMASA S (Kyushu Univ., Kasuga, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 58  Issue： 47  Page： 9613-9620  Publication year： Nov. 18, 2002 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,...
Semi thesaurus term： magnesium cation

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JST classification (1)： Oxazoles,isoxazoles  (CF07080Y)

Substance index (28)： Butoxymagnesium bromide ,  α-Chlorobenzaldehyde oxime ,  4-Chlorobenzhydroximic acid chloride ,  α-Chloro-4-(trifluoromethyl)benzaldehydeoxime ,  Phenethylchloro ketoneoxime ,  (1S,2E)-1-(Trimethylsilyl)-2-hexene-1-ol ,  (1S,2E)-1-(Trimethylsilyl)-2-butene-1-ol ,  (αS,4S)-α-(Trimethylsilyl)-3-phenyl-4α-propyl-2-isoxazoline-5β-methanol ,  (αS,4S)-α-(Trimethylsilyl)-3-(4-chlorophenyl)-4α-propyl-2-isoxazoline-5β-methanol ,  (αS,4S)-α-(Trimethylsilyl)-3-[4-(trifluoromethyl)phenyl]-4α-propyl-2-isoxazoline-5β-methanol ,  (αS,4S)-α-(Trimethylsilyl)-3-phenethyl-4α-propyl-2-isoxazoline-5β-methanol ,  (αS,4S)-α-(Trimethylsilyl)-3-phenyl-4α-methyl-2-isoxazoline-5β-methanol ,  (αS,4S)-α-(Trimethylsilyl)-3-(4-chlorophenyl)-4α-methyl-2-isoxazoline-5β-methanol ,  (αS,4S)-α-(Trimethylsilyl)-3-[4-(trifluoromethyl)phenyl]-4α-methyl-2-isoxazoline-5β-methanol ,  (4R)-3-Phenyl-4-propyl-5,6-dihydro-4H-1,2-oxazine-6-ol ,  (4R)-3-(4-Chlorophenyl)-4-propyl-5,6-dihydro-4H-1,2-oxazine-6-ol ,  (4R)-3-Phenyl-4-methyl-5,6-dihydro-4H-1,2-oxazine-6-ol ,  (4R)-3-[4-(Trifluoromethyl)phenyl]-4-methyl-5,6-dihydro-4H-1,2-oxazine-6-ol ,  (4R)-3-Phenyl-4-propyl-4H-1,2-oxazine-6(5H)-one ,  (4R)-3-Phenyl-4-methyl-4H-1,2-oxazine-6(5H)-one ,  (4R)-3-[4-(Trifluoromethyl)phenyl]-4-methyl-4H-1,2-oxazine-6(5H)-one ,  [(4S)-3-Phenyl-4α-propyl-2-isoxazoline-5α-yl](trimethylsilyl) ketone ,  [(5S)-3-Phenyl-2-isoxazoline-5-yl](trimethylsilyl) ketone ,  (1R)-1-[(4S)-3-Phenyl-4α-propyl-2-isoxazoline-5β-yl]-1-(trimethylsilyl)-3-butene-1-ol ,  (1S)-1-[(4S)-3-Phenyl-4α-propyl-2-isoxazoline-5β-yl]-1-(trimethylsilyl)-3-butene-1-ol ,  (1S)-1-[(4S)-3-Phenyl-4α-propyl-2-isoxazoline-5β-yl]-1-(trimethylsilyl)-3-methyl-3-butene-1-ol ,  (1S)-1-[(5S)-3-Phenyl-2-isoxazoline-5-yl]-1-(trimethylsilyl)-3-butene-1-ol ,  Tetrabutylammonium

Terms in the title (4)： 置換 ,  エナンチオ選択的合成 ,  側鎖 ,  立体