Art

J-GLOBAL ID：200902144446790211   Reference number：01A0569615

The Ruthenium-Catalyzed Addition of βC-H Bonds in Aldehydes to Olefins.

アルデヒドにおけるβC-H結合のオレフィンへのルテニウム触媒付加反応

Author (5)： KAKIUCHI F (Osaka Univ., Osaka) ,  SATO T (Osaka Univ., Osaka) ,  IGI K (Osaka Univ., Osaka) ,  CHATANI N (Osaka Univ., Osaka) ,  MURAI S (Osaka Univ., Osaka)
Material： Chemistry Letters  (Chem Lett)
Issue： 5  Page： 386-387  Publication year： May. 05, 2001 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： C-H bond ,...

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JST classification (3)： Aromatic monocyclic aldehydes  (CF05160X) ,  Alkenes  (CF03030T) ,  Nobel metal catalysts  (CB06122I)

Substance index (26)： Triphenylphosphine ,  Styrene ,  Ethylene ,  2-(Trimethylsilyl)benzaldehyde ,  Vinyltriethoxysilane ,  2-(Trimethylsilyl)-6-[2-(triethoxysilyl)ethyl]benzaldehyde ,  2,4-Di-tert-butylbenzaldehyde ,  2,4-Di-tert-butyl-6-[2-(triethoxysilyl)ethyl]benzaldehyde ,  3,4-Dihydro-2H-pyran-5-carbaldehyde ,  2-[2-(Triethoxysilyl)ethyl]-5,6-dihydro-4H-pyran-3-carbaldehyde ,  Vinyltrimethylsilane ,  3,3-Dimethyl-1-butene ,  Allyltrimethylsilane ,  2-[2-(Trimethylsilyl)ethyl]-5,6-dihydro-4H-pyran-3-carbaldehyde ,  2-(3,3-Dimethylbutyl)-5,6-dihydro-4H-pyran-3-carbaldehyde ,  2-[3-(Trimethylsilyl)propyl]-5,6-dihydro-4H-pyran-3-carbaldehyde ,  2-Phenethyl-5,6-dihydro-4H-pyran-3-carbaldehyde ,  2-Ethyl-5,6-dihydro-4H-pyran-3-carbaldehyde ,  Thiophene-3-carbaldehyde ,  2-[2-(Triethoxysilyl)ethyl]thiophene-3-carbaldehyde ,  2-[2-(Triethoxysilyl)ethyl]thiophene ,  3-Formyl-1-methyl-1H-indole ,  1-Methyl-2-[2-(triethoxysilyl)ethyl]-1H-indole-3-carbaldehyde ,  1-Methyl-2-[2-(triethoxysilyl)ethyl]-1H-indole ,  1-(Trimethylsilyl)-1-propyne ,  1-Methyl-2-[1-methyl-2-(trimethylsilyl)vinyl]-1H-indole-3-carbaldehyde

Reference (13)：

• 1) a) F. Kakiuchi, S. Sekine, Y. Tanaka, A. Kamatani, M. Sonoda, N. Chatani, and S. Murai, Bull. Chem. Soc. Jpn., 68, 62 (1995).
•  b) F. Kakiuchi, Y. Tanaka, T. Sato, N. Chatani, and S. Murai, Chem. Lett., 1995, 679.
•  c) M. Sonoda, F. Kakiuchi, N. Chatani, and S. Murai, Bull. Chem. Soc. Jpn., 70, 3117 (1997).
• 2) M. Sonoda, F. Kakiuchi, N. Chatani, and S. Murai, Chem. Lett., 1996, 109.
• 3) W. P. Weber, H. Guo, C. L. Kepler, M. A. Londergan, M. Timothy, P. Lu, J. Paulsaari, J. R. Sargent, and G. W. Tapsak, ACS Symp. Ser., 729, 433 (2000).

Terms in the title (5)： アルデヒド ,  C-H結合 ,  オレフィン ,  ルテニウム触媒 ,  付加反応